Title: Achiral Cyclopentadienone Iron Tricarbonyl Complexes Embedded in Streptavidin: An Access to Artificial Iron Hydrogenases and Application in Asymmetric Hydrogenation.
Authors: Mérel, Delphine; Gaillard, Sylvain; Ward, Thomas; Renaud, Jean-Luc
Abstract: We report on the synthesis of biotinylated (cyclopentadienone)iron tricarbonyl complexes, the in situ generation of the corresponding streptavidin conjugates and their application in asymmetric hydrogenation of imines and ketones. Graphical Abstract: [Figure not available: see fulltext.]
Subjects: CYCLOPENTADIENE; METAL complexes; IRON compounds; CARBONYL compounds; STREPTAVIDIN; HYDROGENATION; HYDROGENASE
Publication: Catalysis Letters, 2016, Vol 146, Issue 3, p564
ISSN: 1011-372X
Publication type: Academic Journal
DOI: 10.1007/s10562-015-1681-6

Achiral Cyclopentadienone Iron Tricarbonyl Complexes Embedded in Streptavidin: An Access to Artificial Iron Hydrogenases and Application in Asymmetric Hydrogenation.

Mérel, Delphine; Gaillard, Sylvain; Ward, Thomas; Renaud, Jean-Luc