Thermal, mechanical, optical and dielectric properties of piperazinium hydrogen phosphite monohydrate NLO single crystal.

Rajkumar, R.; Praveen Kumar, P.

Optical transparent crystal of piperazinium hydrogen phosphite monohydrate (PHPM) was grown by slow evaporation method. The grown crystal was characterized by single crystal X-ray diffraction analysis and the crystal belongs to monoclinic system. The functional groups present in PHPM crystal were confirmed by FTIR analysis. UV-Visible spectrum shows that the PHPM crystal is transparent in the visible region. The mechanical behavior of PHPM crystal was characterized by Vickers hardness test. Thermal stability of PHPM crystal was analyzed by thermogravimetric analysis. Dielectric studies were also carried out for the grown crystal. The third-order nonlinear parameters such as nonlinear refractive index and nonlinear absorption coefficient have been calculated using Z scan technique.

PHOSPHINE; SINGLE crystals; OPTICAL properties of metals; X-ray diffraction; FOURIER transform infrared spectroscopy

Applied Physics A: Materials Science & Processing, 2018, Vol 124, Issue 5, p1

0947-8396

Academic Journal

10.1007/s00339-018-1783-2