Stoichiometric tin (II) sulfide (SnS) nanostructures were synthesized on SnS(010)/glass substrates using a simple and low-temperature chemical solution method, and their physical properties were investigated. The as-synthesized SnS nanostructures exhibited orthorhombic crystal structure and most of the nanocrystals are preferentially oriented along the direction. These nanostructures showed p-type electrical conductivity and high electrical resistivity of 93 Ωcm. SnS nanostructures exhibited a direct optical band gap of 1.43 eV. While increasing the surrounding temperature from 20 to 150 °C, the electrical resistivity of the structures decreased and exhibited the activation energy of 0.28 eV.