Photoionization cross-section weighted DFT simulations as promising tool for the investigation of the electronic structure of open shell metal-phthalocyanines.

Vogel, Michael; Schmitt, Felix; Sauther, Jens; Baumann, Benedikt; Altenhof, Anna; Lach, Stefan; Ziegler, Christiane

The valence band structure of different metal-phthalocyanines was investigated by comparing ultraviolet photoelectron spectra at different excitation energies with simulated spectra that take the different photoionization cross-sections at these energies into account. The Kohn-Sham eigenvalue spectra, derived from density functional theory calculations, using hybrid exchange-correlation functionals, were weighted with the photoionization coefficients in accordance with the used excitation energy. By applying these techniques, the differences in the photoelectron spectra using He I and He II radiation can be reproduced and investigated. It will be shown that the 3d-orbitals of the used metal central atom of these molecules have a major influence. The changes at different excitation energies were studied for Fe, Co, and Cu central atoms to describe the chemical tailoring effects.

PHTHALOCYANINES; PHOTOELECTRONS; EXCITATION (Physiology); ELECTRONIC structure; EIGENVALUES; FUNCTION spaces

Analytical & Bioanalytical Chemistry, 2011, Vol 400, Issue 3, p673

1618-2642

Academic Journal

10.1007/s00216-011-4785-x