Hydrophobic or hydrophilic microhelices: Crafting surfaces with electrospun magnetic polystyrene fiber and an innovative top‐down technique.

Mohan, Aakanksha; Ramanan, Sutapa Roy

Microhelices are important structures capable of overcoming low Reynolds number limitations and can be used in various applications. The fabrication of such microhelices is a challenge as existing fabrication techniques are restrictive in material choices and require sophisticated equipment. In this work, we demonstrate a simple top‐down approach to fabricate microhelical structures using surface modification of helical electrospun fibers to produce both hydrophilic, silica‐coated (Si‐HMPF), and hydrophobic, caramel sol‐based (Ca‐HMPF) magnetic microhelices post‐modification. The glassy coating obtained on the surface in both cases facilitated obtaining magnetic microhelices via mechanical fracture of the fibers by grinding at room temperature. SEM images of the samples confirm the successful fabrication of microhelical structures which resemble the popular microswimmer morphology. The FTIR and VSM characterization were performed to study the functional groups present and the magnetic nature of the fabricated microhelices. The thermal stability of the samples was investigated using DSC and TGA studies. Both hydrophilic and hydrophobic magnetic microhelices were successfully fabricated through a simple sol‐based coating technique and confirmed by a wettability study. Highlights: Helical microstructures are an important classification of micro/nanomaterial synthesis.A simple method for the fabrication of magnetic polymeric microhelices is proposed and discussed in detail.The current challenges in fabricating such structures are discussed.The advantages of using a simple surface modification technique is summarized.

GLASS coatings; REYNOLDS number; THERMAL stability; SCANNING electron microscopy; FUNCTIONAL groups; HYDROPHOBIC surfaces

Polymer Engineering & Science, 2024, Vol 64, Issue 9, p4332

0032-3888

Academic Journal

10.1002/pen.26851