Results
Title

Comparison of homofugality among alkyl groups attached to tin atom.

Authors

Kamimura, Akio; Yoshinaga, Tatsuro; Miyazaki, Koichiro; Kawamoto, Takuji

Abstract

Dibutylmethyltin hydride and tert‐butyldibutyltin hydride were employed to examine radical cascade reaction of aza‐1,6‐enyne for the preliminary estimation of homofugality between alkyl groups by product distribution analysis. Use of either dibutylmethyltin hydride or tert‐butyldibutyltin hydride preferentially produced butylmethylstannolane, in which butyl group was mainly substituted by vinyl radical.

Subjects

HYDRIDE transfer reactions; HYDRIDE electrodes; OLIGOMERIZATION; ORGANIC chemistry; CHEMICAL reactions

Publication

Heteroatom Chemistry, 2018, Vol 29, Issue 5/6, pN.PAG

ISSN

1042-7163

Publication type

Academic Journal

DOI

10.1002/hc.21469