The reaction OF N-dichlorophosphoryl- P-trichlorophosphazene with alkyl grignard reagents.

Aslan, F.; Ozturk, A. I.; Arslan, M.

The reactions of N-dichlorophosphoryl-P-trichlorophosphazene Cl3PNP(O)Cl2 ( 1) with benzylmagnesium bromide, 2-phenylethylmagnesium bromide, trimethylsilylmethylmagnesium chloride, n-butylmagnesium bromide, cyclohexylmagnesium bromide, cyclopentylmagnesium bromide, tert-butylmagnesium bromide, iso-propylmagnesium bromide, and ethylmagnesium bromide were studied. Tri- and pentaalkyl phosphazenes were obtained in very poor yield from trimethylsilylmethylmagnesium chloride and cyclohexylmagnesium bromide, respectively. Trialkylphosphoryl compounds formed from benzyl-, 2-phenylethyl-, and n-butylmagnesium bromide. No phosphorus compound could be isolated from the reaction of 1 with t-butyl-, cyclopentyl-, iso-propyl-, and ethylmagnesium bromide. © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:413-416, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10153

Heteroatom Chemistry, 2003, Vol 14, Issue 5, p413

1042-7163

Academic Journal

10.1002/hc.10153