Title: Visible‐Light‐Induced Bromination of α‐Diazo Compounds with Bromoform.
Authors: Zhang, Xin; Lin, Junyue; Liu, Miao‐Chang; Zhou, Yun‐Bing; Wu, Hua‐Yue
Abstract: An efficient visible‐light‐driven strategy for bromination of α‐diazo compounds is achieved for the construction of α‐bromoesters with bromoform. It is noteworthy that the reaction occurs under sole light irradiation without a photocatalyst or an additive. Several synthetic transformations and gram‐scale reactions demonstrate the synthetic potential of this photochemical reaction.
Subjects: BROMOFORM; DIAZO compounds; VISIBLE spectra
Publication: European Journal of Organic Chemistry, 2024, Vol 27, Issue 4, p1
ISSN: 1434-193X
Publication type: Academic Journal
DOI: 10.1002/ejoc.202300958

Visible‐Light‐Induced Bromination of α‐Diazo Compounds with Bromoform.

Zhang, Xin; Lin, Junyue; Liu, Miao‐Chang; Zhou, Yun‐Bing; Wu, Hua‐Yue