Title: Synthesis and Characterization of the Trichlates [N(CH3)4][Cl3CSO3], [NH4][Cl3CSO3], and the Dichlate [NH4][Cl2CHSO3].
Authors: Mertens, Alisha; van Gerven, David; Lee, Hyunsong; Wickleder, Mathias S.
Abstract: This article, published in the European Journal of Inorganic Chemistry, provides information on the synthesis and characterization of trichlates, which are larger versions of triflates. The crystal structures of two trichlate compounds, NH4[Cl3CSO3] and (NH4)[Cl2CHSO3], are described, along with their properties and thermal analyses. The article also discusses the accidental synthesis of (NH4)[Cl2CHSO3] and the need for a reliable synthesis protocol for the [Cl2CHSO3]− anion. This research aims to contribute to the understanding of trichlates and their comparison to triflates.
Subjects: PHASE transitions; SERVER farms (Computer network management)
Publication: European Journal of Inorganic Chemistry, 2024, Vol 27, Issue 4, p1
ISSN: 1434-1948
Publication type: Academic Journal
DOI: 10.1002/ejic.202300535

Synthesis and Characterization of the Trichlates [N(CH<sub>3</sub>)<sub>4</sub>][Cl<sub>3</sub>CSO<sub>3</sub>], [NH<sub>4</sub>][Cl<sub>3</sub>CSO<sub>3</sub>], and the Dichlate [NH<sub>4</sub>][Cl<sub>2</sub>CHSO<sub>3</sub>].

Mertens, Alisha; van Gerven, David; Lee, Hyunsong; Wickleder, Mathias S.