Title: K3[MO4][MO3N] (M=Tc, Re) – Nitridotrioxidorhenate and ‐technetate from Highly Alkaline Media.
Authors: Badea, Désirée; Olthof, Selina; Neudörfl, Jörg M.; Glaum, Robert; Pöttgen, Rainer; Reimann, Maximilian Kai; Meerholz, Klaus; Reimer, Max; Logemann, Christian; Strub, Erik; Bruns, Jörn
Abstract: The reactions of ammonium perrhenate and pertechnetate in highly alkaline medium led to the isotypic mixed anionic nitridotrioxidorhenate and ‐technetate K3[MO4][MO3N] (M= Tc, Re). Both compounds occur as colorless crystals, which were investigated by single crystal X‐ray diffraction. Furthermore, K3[ReO4][ReO3N] has been studied by means of X‐ray photoelectron spectroscopy to determine the oxidation state of rhenium. The obtained results have been complemented by magnetic measurements. IR and Raman spectroscopy indicated the presence of Re−O as well as Re−N bonds.
Subjects: X-ray photoelectron spectroscopy; RAMAN spectroscopy; SINGLE crystals; MAGNETIC measurements; OXIDATION states
Publication: European Journal of Inorganic Chemistry, 2023, Vol 26, Issue 26, p1
ISSN: 1434-1948
Publication type: Academic Journal
DOI: 10.1002/ejic.202300160

K<sub>3</sub>[MO<sub>4</sub>][MO<sub>3</sub>N] (M=Tc, Re) – Nitridotrioxidorhenate and ‐technetate from Highly Alkaline Media.

Badea, Désirée; Olthof, Selina; Neudörfl, Jörg M.; Glaum, Robert; Pöttgen, Rainer; Reimann, Maximilian Kai; Meerholz, Klaus; Reimer, Max; Logemann, Christian; Strub, Erik; Bruns, Jörn