Chalcogen Bonding in Selective Recognition and Liquid‐Liquid Extraction of Perrhenate.

Pramanik, Sourav; Islam, Abu S. M.; Ghosh, Iti; Ghosh, Pradyut

Efficient recognition and extraction of hazardous anionic pollutants from water medium is of great significance for environmental concerns, representing a challenging area of research in supramolecular chemistry. In this study, we present, for the first time, a comprehensive demonstration of the ability of chalcogen bonding (ChB) to recognize and remove the ReO4− from 100 % water medium. The anion recognition ability is well elucidated through solution phase NMR and ITC studies, which clearly reveal the selective binding of ReO4− over other oxo‐anions. Moreover, the selenoimidazolium scaffold effectively engages in Se•••O ChB interaction with ReO4− as confirmed by X‐ray crystal structure and XPS analysis. More importantly, the binding of ReO4− with different prolongations of the σ–holes, along with Se•••Se chalcogen bonding interactions, lead to the formation of a 1D supramolecular assembly. Eventually, ChB receptor Se4Me−Br exhibits ~62 % ReO4− extraction efficiency through precipitation as the extraction method. Furthermore, in efforts to enhance efficiency, a hydrophobic ChB receptor Se4Do‐PF6 has been prepared, achieving an efficiency of up to ~93 % at a very low concentration (~5 ppm) by liquid‐liquid extraction.

PRECIPITATION (Chemistry); SUPRAMOLECULAR chemistry; LIQUID-liquid extraction; WATER pollution; X-ray diffraction

Chemistry - A European Journal, 2024, Vol 30, Issue 53, p1

0947-6539

Academic Journal

10.1002/chem.202402153