Title: A Preference for Heterolepticity ‐ Schlenk Type Equilibria in Organometallic Beryllium Systems.
Authors: Buchner, Magnus R.; Thomas‐Hargreaves, Lewis R.; Berthold, Chantsalmaa; Bekiş, Deniz F.; Ivlev, Sergei I.
Abstract: BePhX1.91.9-0.3THFBePhX vs. Keywords: beryllium; Grignard compounds; ligand exchange; organometallics; Schlenk equilibrium EN beryllium Grignard compounds ligand exchange organometallics Schlenk equilibrium 1 13 13 10/31/23 20231026 NES 231026 B The reaction of homoleptic beryllium halide b with diphenyl beryllium complexes leads to the clean formation of heteroleptic beryllium I Grignard i compounds [(L) SB 1-2 sb BePh I X i ] SB 1-2 sb ( I X i =Cl, Br, I; L= I C i -, I N i -, I O i -donor ligand). BePhX7.12.91.7NEt3BePhX vs.
Subjects: BERYLLIUM; CHEMICAL shift (Nuclear magnetic resonance); ALKALINE earth metals; ATOMS; LIGAND exchange reactions; MIXTURES
Publication: Chemistry - A European Journal, 2023, Vol 29, Issue 60, p1
ISSN: 0947-6539
Publication type: Academic Journal
DOI: 10.1002/chem.202302495

A Preference for Heterolepticity ‐ Schlenk Type Equilibria in Organometallic Beryllium Systems.

Buchner, Magnus R.; Thomas‐Hargreaves, Lewis R.; Berthold, Chantsalmaa; Bekiş, Deniz F.; Ivlev, Sergei I.