Results
Title

Cover Feature: Polycations Stabilised by Borosulfates: [Au<sub>3</sub>Cl<sub>4</sub>][B(S<sub>2</sub>O<sub>7</sub>)<sub>2</sub>] and the One‐Dimensional Metal [Au<sub>2</sub>Cl<sub>4</sub>][B(S<sub>2</sub>O<sub>7</sub>)<sub>2</sub>](SO<sub>3</sub>) (Chem. Eur. J. 22/2022)

Authors

Sutorius, Stefan; van Gerven, David; Olthof, Selina; Rasche, Bertold; Bruns, Jörn

Abstract

Keywords: borosulfates; crystal structures; electronic structures; one-dimensional metals; polycations EN borosulfates crystal structures electronic structures one-dimensional metals polycations 1 1 1 04/21/22 20220419 NES 220419 B Single crystals b of [Au SB 3 sb Cl SB 4 sb ][B(S SB 2 sb O SB 7 sb ) SB 2 sb ] and [Au SB 2 sb Cl SB 4 sb ][B(S SB 2 sb O SB 7 sb ) SB 2 sb ](SO SB 3 sb ) were obtained from a solvothermal reaction with SO SB 3 sb , and their electronic properties were investigated by means of density functional theory-based calculations. Cover Feature: Polycations Stabilised by Borosulfates: [Au3Cl4][B(S2O7)2] and the One-Dimensional Metal [Au2Cl4][B(S2O7)2](SO3) (Chem. Eur. J. 22/2022) [Au SB 3 sb Cl SB 4 sb ][B(S SB 2 sb O SB 7 sb ) SB 2 sb ] exhibits a cluster-like cation, and the cationic gold-chloride strands in [Au SB 2 sb Cl SB 4 sb ][B(S SB 2 sb O SB 7 sb ) SB 2 sb ](SO SB 3 sb ) are found to resemble one-dimensional metallic wires; this was further confirmed by polarization microscopy.

Subjects

METALS; POLARIZATION microscopy; ELECTRONIC structure; METALLIC wire

Publication

Chemistry - A European Journal, 2022, Vol 28, Issue 22, p1

ISSN

0947-6539

Publication type

Academic Journal

DOI

10.1002/chem.202200922