Controllable Zeolite AST Crystallization: Between Classical and Reversed Crystal Growth.

Yue, Qiudi; Kutukova, Kristina; Li, Ang; Čejka, Jiří; Zschech, Ehrenfried; Opanasenko, Maksym

Crystal growth mechanisms govern a wide range of properties of crystalline materials. Reversed crystal growth is one of the nonclassical mechanisms observed in many materials. However, the reversed crystallization starting from amorphous aggregates and the key factors driving this growth remain elusive. Here, we describe a characteristic model of reversed crystal growth representing the inner structure and crystallinity development of aggregates studied by microscopy and nano X‐ray computed tomography. By adjusting the synthesis conditions, the fundamental function of the structure‐directing agent, which determines the crystallization pathway, was revealed. As a result, the crystal growth mode can be "switched" from the classical route at a low ratio of SDA/framework elements to reversed growth at a high ratio. Our findings provide further insights into crystal growth control, which is crucial for improving synthesis protocols and designing various forms of crystalline materials.

CRYSTAL growth; COMPUTED tomography; CRYSTALLIZATION; ZEOLITES; CRYSTAL models

Chemistry - A European Journal, 2022, Vol 28, Issue 35, p1

0947-6539

Academic Journal

10.1002/chem.202200590