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- Title
Intermolecular Hydroaminoalkylation of Alkynes.
- Authors
Kaper, Tobias; Fischer, Malte; Thye, Hermann; Geik, Dennis; Schmidtmann, Marc; Beckhaus, Ruediger; Doye, Sven
- Abstract
Intermolecular hydroaminoalkylation reactions of alkynes with secondary amines, which selectively give access to allylic amines with E configuration of the alkene unit, are achieved in the presence of titanium catalysts. Successful reactions of symmetrically substituted diaryland dialkylalkynes as well as a terminal alkyne take place with N-benzylanilines, N-alkylanilines, and N-alkylbenzylamines.
- Subjects
ALKYNES; TITANIUM catalysts; SECONDARY amines; AMINES
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 23, p6899
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.202100238