We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Redox‐Neutral Tetrafluoroethylation of Aryl Alkynes with 1,1,2,2‐Tetrafluoroethane Sulfonic Acid Leading to α‐Tetrafluoroethylated Acetophenones.
- Authors
Kawamoto, Takuji; Noguchi, Kohki; Takata, Ryotaro; Sasaki, Rio; Matsubara, Hiroshi; Kamimura, Akio
- Abstract
The redox‐neutral tetrafluoroethylation of alkynes with 1,1,2,2‐tetrafluroroethanesulfonic acid (TFESA) and azobis(isobutyronitrile) (AIBN) proceeds via the formation of vinyl tetrafluoroethanesulfonates followed by a radical tetrafluoroethylation. Experimental and theoretical results support an intermolecular reaction.
- Subjects
ACETOPHENONE; ALKYNES
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 37, p9529
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.202100137