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- Title
Metal‐Free Synthesis of Aryl Selenocyanates and Selenaheterocycles with Elemental Selenium.
- Authors
Zhang, Xue; Huang, Xiao‐Bo; Zhou, Yun‐Bing; Liu, Miao‐Chang; Wu, Hua‐Yue
- Abstract
This work reports a green method for the synthesis of aryl selenocyanates via a three‐component reaction of arylboronic acids, Se powder, and trimethylsilyl cyanide (TMSCN) under metal‐free and additive‐free conditions. Remarkably, TMSCN acts as not only the substrate, but also the catalyst. Various selenaheterocycles can be also accessed with a catalytic amount of TMSCN.
- Subjects
ENVIRONMENTAL reporting; SELENIUM; CYANIDES; POWDERS; CATALYSTS
- Publication
Chemistry - A European Journal, 2021, Vol 27, Issue 3, p944
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.202004005