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- Title
Palladium‐Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion.
- Authors
Sakurai, Yuka; Ogiwara, Yohei; Sakai, Norio
- Abstract
A palladium‐catalyzed annulation of acyl fluorides with norbornene is described. This study reports the first example of an annulation of acyl fluorides in the presence of a transition‐metal catalyst. Polycyclic ketones are obtained from the cleavage of the C−F and C−H bonds of the acyl fluoride and the rearrangement of the carbonyl moiety by decarbonylation and CO reinsertion.
- Subjects
DECARBONYLATION; ANNULATION; FLUORIDES; CATALYSTS; MOIETIES (Chemistry)
- Publication
Chemistry - A European Journal, 2020, Vol 26, Issue 57, p12972
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.202001374