Title: Palladium‐Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion.
Authors: Sakurai, Yuka; Ogiwara, Yohei; Sakai, Norio
Abstract: A palladium‐catalyzed annulation of acyl fluorides with norbornene is described. This study reports the first example of an annulation of acyl fluorides in the presence of a transition‐metal catalyst. Polycyclic ketones are obtained from the cleavage of the C−F and C−H bonds of the acyl fluoride and the rearrangement of the carbonyl moiety by decarbonylation and CO reinsertion.
Subjects: DECARBONYLATION; ANNULATION; FLUORIDES; CATALYSTS; MOIETIES (Chemistry)
Publication: Chemistry - A European Journal, 2020, Vol 26, Issue 57, p12972
ISSN: 0947-6539
Publication type: Academic Journal
DOI: 10.1002/chem.202001374

Palladium‐Catalyzed Annulation of Acyl Fluorides with Norbornene via Decarbonylation and CO Reinsertion.

Sakurai, Yuka; Ogiwara, Yohei; Sakai, Norio