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- Title
Chiral Benzazaborole‐Catalyzed Regioselective Sulfonylation of Unprotected Carbohydrate Derivatives.
- Authors
Kuwano, Satoru; Hosaka, Yusei; Arai, Takayoshi
- Abstract
Chiral benzazaborole‐catalyzed regioselective sulfonylations of unprotected carbohydrate derivatives have been developed. This methodology enables direct regioselective functionalization of the secondary OH group in carbohydrate in the presence of the primary OH group. By using the chiral organoboron catalysis, kinetic resolution of the carbohydrate derivatives was also achieved.
- Subjects
CARBOHYDRATES; ENANTIOSELECTIVE catalysis; KINETIC resolution; DIPYRRINS; COMPLEX organizations; RACEMIC mixtures
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 56, p12920
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.201903443