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Title: Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re6−xMoxSe8(CN)6]n−.
Authors: Muravieva, Viktoria K.; Gayfulin, Yakov M.; Prestipino, Carmelo; Lemoine, Pierric; Ryzhikov, Maxim R.; Yanshole, Vadim V.; Cordier, Stéphane; Naumov, Nikolay G.
Abstract: Influence of the metal core composition and geometry on the structure, spectroscopic properties and redox potentials was investigated for the first time for heterometallic (Re/Mo)6 octahedral clusters. The discrete anionic clusters [Re6‐xMoxSe8(CN)6]n− (x=2, 3; n=4, 5) were obtained as individual salts. Their isomeric composition and bond‐length distribution were inspected using a combination of single‐crystal X‐ray structure analysis, NMR, EXAFS, and DFT calculations.
Subjects: REDUCTION potential; MOLYBDENUM; ELECTRONIC structure
Publication: Chemistry - A European Journal, 2019, Vol 25, Issue 66, p15040
ISSN: 0947-6539
Publication type: Academic Journal
DOI: 10.1002/chem.201903321

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Tailoring Heterometallic Cluster Functional Building Blocks: Synthesis, Separation, Structural and DFT Studies of [Re<sub>6−x</sub>Mo<sub>x</sub>Se<sub>8</sub>(CN)<sub>6</sub>]<sup>n−</sup>.