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Title: Cover Feature: Synthesis and Characterization of Pheox– and Phebox–Aluminum Complexes: Application as Tunable Lewis Acid Catalysts in Organic Reactions (Chem. Eur. J. 46/2019).
Authors: Nishimoto, Yoshihiro; Nakao, Shuichi; Machinaka, Shota; Hidaka, Fumiko; Yasuda, Makoto
Abstract: Highlights from the article: B Novel organoaluminum catalysts b , 2-oxazolinylphenylaluminum (Pheox-Al) and 2,6-bis(oxazolinyl)phenylaluminum (Phebox-Al) complexes, were synthesized. Phebox-Al(OTf) SB 2 sb had a much higher catalytic activity than typical inorganic Al salts such as AlCl SB 3 sb and Al(OTf) SB 3 sb in hydroboration of aldehydes. Lewis acids, aluminum, ligand design, hydrocarbyl ligand, organic aluminums.
Subjects: LEWIS acids; ACID catalysts; ORGANIC acids; LEWIS acidity; CATALYTIC activity
Publication: Chemistry - A European Journal, 2019, Vol 25, Issue 46, p10764
ISSN: 0947-6539
Publication type: Academic Journal
DOI: 10.1002/chem.201902970

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Cover Feature: Synthesis and Characterization of Pheox– and Phebox–Aluminum Complexes: Application as Tunable Lewis Acid Catalysts in Organic Reactions (Chem. Eur. J. 46/2019).