We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Organocatalytic Formal Intramolecular [3 2]‐Cycloaddition to Acquire Biologically Important Methanodibenzo[a,f]azulenes and Methanobenzo[f]azulenes.
- Authors
Peraka, Swamy; Pasha, Mohammed Anif; Thirupathi, Guguloth; Ramachary, Dhevalapally B.
- Abstract
Lawsones were transformed into the functionally rich framework of methanodibenzo[a,f]azulenes and methanobenzo[f]azulenes in a single‐ or two‐pot operation through five organocatalytic sequential reactions in very good yields with excellent selectivities. These resultant molecules are basic skeletons of important antibiotics, which highlights the value of this formal intramolecular [3 2]‐cycloaddition as a key protocol.
- Subjects
ANTIBIOTICS; SKELETON; MOLECULES; CONDENSATION; ASYMMETRIC synthesis
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 62, p14036
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.201902453