Results
Title

Support‐Free Pd<sub>3</sub>Co NCs as an Efficient Heterogeneous Nanocatalyst for New Organic Transformations of C−C Coupling Reactions.

Authors

Pradhan, Samjhana; Mishra, Kanchan; Lee, Yong Rok

Abstract

A support‐free heterogeneous Pd3Co nanostructured composite (NC), synthesized through a hydrothermal route, acted as an effective catalytic system in multivariate Heck‐, Sonogashira‐, and Suzuki‐type coupling reactions of iodonium ylides. The XPS analysis of the bimetallic Pd3Co NCs confirmed the elemental composition as 75 % palladium and 25 % cobalt. Furthermore, high‐resolution (HR) TEM analysis confirmed the spherical morphology of the Pd3Co bimetallic nanoparticles. The average diameter of the NCs is 14.8 nm. The coupling reaction proceeded through the generation of α‐iodoenones with simultaneous migration of the phenyl group, thereby giving a scaffold with higher atom economy. The heterogeneous Pd3Co NCs were recycled and reused without any significant change in catalytic ability for up to five reaction cycles. The high concentration of Pd and association of cobalt into the lattice of palladium appears to enhance its catalytic ability for the diverse coupling reactions in comparison with its monometallic counterparts as well as with bimetallic NCs with a comparatively lesser amount of Pd.

Subjects

COBALT; NANOCOMPOSITE materials; PHENYL group; BIMETALLIC catalysts; WASTE recycling; PALLADIUM

Publication

Chemistry - A European Journal, 2019, Vol 25, Issue 46, p10886

ISSN

0947-6539

Publication type

Academic Journal

DOI

10.1002/chem.201901834