Results
Title

Nickel‐Copper‐Catalyzed Hydroacylation of Vinylarenes with Acyl Fluorides and Hydrosilanes.

Authors

Ueda, Yusuke; Iwai, Tomohiro; Sawamura, Masaya

Abstract

The hydroacylation of vinylarenes with acyl fluorides and hydrosilanes was enabled by a synergistic bimetallic Ni/Cu‐catalytic system, giving access to the corresponding branched ketone products. The reaction takes place under mild conditions at 25–80 °C and tolerates base‐sensitive functional groups such as methoxycarbonyl and acetoxy groups.

Subjects

FUNCTIONAL groups; FLUORIDES

Publication

Chemistry - A European Journal, 2019, Vol 25, Issue 40, p9410

ISSN

0947-6539

Publication type

Academic Journal

DOI

10.1002/chem.201900822