We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Thiadiazolo‐Azaacenes.
- Authors
Müller, Matthias; Koser, Silke; Tverskoy, Olena; Rominger, Frank; Freudenberg, Jan; Bunz, Uwe H. F.
- Abstract
This work reports the synthesis and characterization of bis‐ and tetrakis(thiadiazolo)‐appended di‐ and tetraazaacenes, displaying up to seven catenated benzene/pyrazine rings. The targets are obtained by condensation of benzo‐bis(thiadiazole)‐4,5‐dione with aromatic di‐ and tetraamines. The condensation products—up to a heptacene‐like species—are stable but can be insoluble. Soluble derivatives are readily processible, but do not show enhanced electron affinities, as the two or four attached benzothiadiazole units are effectively resonance‐separated from the acene body, maximizing the number of Clar‐sextets.
- Subjects
X-ray crystallography; THIADIAZOLES; ACENES; CHEMICAL synthesis; CONDENSATION products (Chemistry)
- Publication
Chemistry - A European Journal, 2019, Vol 25, Issue 24, p6082
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.201900462