Title: Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks.
Authors: Adonin, Sergey A.; Bondarenko, Mikhail A.; Abramov, Pavel A.; Novikov, Alexander S.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.
Abstract: Abstract: Cation‐dependent reactions “[SbBr6]3− Br2 HBr CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1).
Subjects: CRYSTAL structure; CHEMICAL reactions; BROMIDES; ANTIMONY; SUPRAMOLECULAR chemistry; THERMOGRAVIMETRY
Publication: Chemistry - A European Journal, 2018, Vol 24, Issue 40, p10165
ISSN: 0947-6539
Publication type: Academic Journal
DOI: 10.1002/chem.201801338

Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks.

Adonin, Sergey A.; Bondarenko, Mikhail A.; Abramov, Pavel A.; Novikov, Alexander S.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.