We found a match
Your institution may have access to this item. Find your institution then sign in to continue.
- Title
Bromo‐ and Polybromoantimonates(V): Structural and Theoretical Studies of Hybrid Halogen‐Rich Halometalate Frameworks.
- Authors
Adonin, Sergey A.; Bondarenko, Mikhail A.; Abramov, Pavel A.; Novikov, Alexander S.; Plyusnin, Pavel E.; Sokolov, Maxim N.; Fedin, Vladimir P.
- Abstract
Abstract: Cation‐dependent reactions “[SbBr6]3− Br2 HBr CationBrx” result in the formation of bromide/polybromide complexes with zero‐, one‐, two‐, or three‐dimensional supramolecular frameworks and different Br/Sb ratios (up to 11). Seven new compounds representing six structural types were characterized by XRD and thermogravimetric analysis and DFT calculations enabled estimation of the energies of the Br⋅⋅⋅Br contacts (1.1–4.6 kcal mol−1).
- Subjects
CRYSTAL structure; CHEMICAL reactions; BROMIDES; ANTIMONY; SUPRAMOLECULAR chemistry; THERMOGRAVIMETRY
- Publication
Chemistry - A European Journal, 2018, Vol 24, Issue 40, p10165
- ISSN
0947-6539
- Publication type
Academic Journal
- DOI
10.1002/chem.201801338