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Title: Rhodium/bisphosphite catalytic system for.
Authors: Zheng, Cong ‐ ye; Mo, Min; Liang, Hao ‐ ran; Zheng, Xue ‐ li; Fu, Hai ‐ yan; Yuan, Mao ‐ lin; Li, Rui ‐ xiang; Chen, Hua
Abstract: Different kinds of mono- and bidentate phosphite ligands were used in Rh-catalyzed of styrene to illustrate the influence of steric and electronic properties of ligands on catalytic performance. High activity (99.9%) and good regioselectivity (85.4%) to the linear aldehyde were achieved under optimum conditions in the presence of Rh/bisphosphite complex (bisphosphite: 2,2′-bis(dipyrrolylphosphinooxy)-1,1′-(±)-binaphthyl). This system makes it possible to prepare functionalized terminal aldehydes from readily available styrene or its derivatives through with high linear selectivity. Copyright © 2013 John Wiley & Sons, Ltd.
Subjects: RHODIUM; BENZENE; ALDEHYDES; STYRENE; HYDROFORMYLATION
Publication: Applied Organometallic Chemistry, 2013, Vol 27, Issue 8, p474
ISSN: 0268-2605
Publication type: Academic Journal
DOI: 10.1002/aoc.3009

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Rhodium/bisphosphite catalytic system for.