Title: HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.
Authors: Hinz, Alexander; Goicoechea, Jose M.; Labbow, René; Schulz, Axel; Rennick, Chris
Abstract: We describe the isolation and spectroscopic characterization of the heavier phosphorus-containing analogue of isocyanic acid (HPCO), and its isotopologue (DPCO). This fundamental small molecule, which has been postulated to exist in interstellar space, has thus far only been observed at low gas phase concentrations or in inert gas matrices. In this report we describe its synthesis, spectroscopic properties, and reactivity in solution.
Subjects: ISOCYANIC acid; ISOTOPOLOGUES; MOLECULAR spectroscopy; SMALL molecules; PHOSPHINIDENES; CARBENE analogues
Publication: Angewandte Chemie International Edition, 2017, Vol 56, Issue 14, p3911
ISSN: 1433-7851
Publication type: Academic Journal
DOI: 10.1002/anie.201700368

HPCO-A Phosphorus-Containing Analogue of Isocyanic Acid.

Hinz, Alexander; Goicoechea, Jose M.; Labbow, René; Schulz, Axel; Rennick, Chris