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- Title
Inside Cover: The Topochemical Pseudomorphosis of a Chloride into a Bismuthide (Angew. Chem. Int. Ed. 12/2014).
- Authors
Kaiser, Martin; Rasche, Bertold; Ruck, Michael
- Abstract
Although apparently trapped in the intermetallic framework of Bi12Rh3Cl2, the Cl ions can be replaced quantitatively by Bi atoms under mild conditions to yield the metastable intermetallic phase Bi14Rh3. M. Ruck et al. show in their Communication on page 3254 ff. that this transport of ions must occur through the seemingly dense framework. The unexpected flexibility of the intermetallic network of edge‐sharing [RhBi8] cubes and antiprisms allows an unusual breathing mode to open large diffusion paths that enable efficient mass transport.
- Subjects
CHEMISTRY periodicals; MAGAZINE covers
- Publication
Angewandte Chemie International Edition, 2014, Vol 53, Issue 12, p3036
- ISSN
1433-7851
- Publication type
Academic Journal
- DOI
10.1002/anie.201401088