Evaluation of Active Oxygen Species Derived from Water Splitting for Electrocatalytic Organic Oxidation.

Yang, Jiangrong; Xia, Tian; Li, Hao; Yan, Hong; Kong, Xianggui; Li, Zhenhua; Shao, Mingfei; Duan, Xue

Active oxygen species (OH*/O*) derived from water electrolysis are essential for the electrooxidation of organic compounds into high‐value chemicals, which can determine activity and selectivity, whereas the relationship between them remains unclear. Herein, using glycerol (GLY) electrooxidation as a model reaction, we systematically investigated the relationship between GLY oxidation activity and the formation energy of OH* (ΔGOH*). We first identified that OH* on Au demonstrates the highest activity for GLY electrooxidation among various pure metals, based on experiments and density functional theory, and revealed that ΔGOH* on Au‐based alloys is influenced by the metallic composition of OH* coordination sites. Moreover, we observed a linear correlation between the adsorption energy of GLY (Eads) and the d‐band center of Au‐based alloys. Comprehensive microkinetic analysis further reveals a volcano relationship between GLY oxidation activity, the ΔGOH* and the adsorption free energy of GLY (ΔGads). Notably, Au3Pd and Au3Ag alloys, positioned near the peak of the volcano plot, show excellent activity, attributed to their moderate ΔGOH* and ΔGads, striking a balance that is neither too high nor too low. This research provides theoretical insights into modulating active oxygen species from water electrolysis to enhance organic electrooxidation reactions.

DENSITY functional theory; ORGANIC compounds; ALLOYS; VOLCANOES; ELECTROCATALYSIS

Angewandte Chemie, 2025, Vol 137, Issue 1, p1

0044-8249

Academic Journal

10.1002/ange.202413457