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- Title
Large Scale Synthesis of a Stable Prefunctionalized Silver Nanocluster.
- Authors
He, Rui‐Lin; Hu, Feng; Guan, Zong‐Jie; Wang, Quan‐Ming
- Abstract
Due to the stability issue, It is difficult to prepare a silver nanocluster bearing functional sites, especially at a large scale. We report the synthesis and structure of a stable silver nanocluster bearing multiple surface aldehyde groups [Ag21(Ph2PO2)10(p‐CHOPhC≡C)6]SbF6, which allows for postsynthesis modification such as surface functionalization through aldimine condensation to give homochiral clusters. Remarkably, the preparation of this cluster can be done in ~90 % high yield at gram scale, which facilitates further studies and potential applications. Through DFT calculations and geometric structure analysis, the high stability of this cluster is attributed to the geometric closure and electronic structure. This is the first time that an effective one‐pot method has been developed to synthesize functional silver nanoclusters in high yield. The title cluster will be useful in the development of a variety of cluster‐based materials.
- Subjects
GEOMETRIC analysis; LIGANDS (Chemistry); ELECTRONIC structure; SILVER; CONDENSATION
- Publication
Angewandte Chemie, 2024, Vol 136, Issue 40, p1
- ISSN
0044-8249
- Publication type
Academic Journal
- DOI
10.1002/ange.202410827