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- Title
Nickel‐Catalyzed, Regio‐ and Enantioselective Benzylic Alkenylation of Olefins with Alkenyl Bromide.
- Authors
Liu, Jiandong; Gong, Hegui; Zhu, Shaolin
- Abstract
A NiH‐catalyzed migratory hydroalkenylation reaction of olefins with alkenyl bromides has been developed, affording benzylic alkenylation products with high yields and excellent chemoselectivity. The mild conditions of the reaction preclude olefinic products from undergoing further isomerization or subsequent alkenylation. Catalytic enantioselective hydroalkenylation of styrenes was achieved by using a chiral bisoxazoline ligand.
- Subjects
ALKENYLATION; ALKENES; BROMIDES; ISOMERIZATION; STYRENE; ALKENYL group; CHEMOSELECTIVITY; ENANTIOSELECTIVE catalysis
- Publication
Angewandte Chemie, 2021, Vol 133, Issue 8, p4106
- ISSN
0044-8249
- Publication type
Academic Journal
- DOI
10.1002/ange.202012614