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- Title
Nickel‐Catalyzed Conversion of Enol Triflates into Alkenyl Halides.
- Authors
Hofstra, Julie L.; Poremba, Kelsey E.; Shimozono, Alex M.; Reisman, Sarah E.
- Abstract
A Ni‐catalyzed halogenation of enol triflates was developed and it enables the synthesis of a broad range of alkenyl iodides, bromides, and chlorides under mild reaction conditions. The reaction utilizes inexpensive, bench‐stable Ni(OAc)2⋅4 H2O as a precatalyst and proceeds at room temperature in the presence of sub‐stoichiometric Zn and either 1,5‐cyclooctadiene or 4‐(N,N‐dimethylamino)pyridine.
- Subjects
HALIDES; IODIDES; HALOGENATION; BROMIDES; WATER; ALKENYL group; ARYL iodides
- Publication
Angewandte Chemie, 2019, Vol 131, Issue 42, p15043
- ISSN
0044-8249
- Publication type
Academic Journal
- DOI
10.1002/ange.201906815