Results
Title

Trifluoromethylfluorosulfonylation of Unactivated Alkenes Using Readily Available Ag(O<sub>2</sub>CCF<sub>2</sub>SO<sub>2</sub>F) and N-Fluorobenzenesulfonimide.

Authors

Liu, Yongan; Wu, Hao; Guo, Yong; Xiao, Ji‐Chang; Chen, Qing‐Yun; Liu, Chao

Abstract

Presented is a novel intermolecular radical trifluoromethylfluorosulfonylation of unactivated alkenes under mild reaction conditions with good functional-group tolerance in the most atom-economic manner by using readily available Ag(O2CCF2SO2F) and N-fluorobenzenesulfonimide (NFSI). Both the trifluoromethyl and sulfonyl groups in the products originate from Ag(O2CCF2SO2F).

Subjects

TRIFLUOROMETHYL compounds; ALKENES; SILVER nanoparticles; IMIDES; FLUOROBENZENE

Publication

Angewandte Chemie, 2017, Vol 129, Issue 48, p15634

ISSN

0044-8249

Publication type

Academic Journal

DOI

10.1002/ange.201709663