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Preparation and Characterization of an Air-Tolerant 1,3-Diphosphacyclobuten-4-yl RadicalThis work was supported in part by Grants-in-Aid for Scientific Research (Nos 13304049 and 14044012) from the Ministry of Education, Culture, Sports, Science and Technology, Japan; the National Science Foundation (CHE-0413521, -0342921, and -0079498; USA); and the US Department of Energy (Grant DE-FG02-86ER13465). We thank Prof. Noboru Morita at Tohoku University for his helpful suggestions and comments.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4447, doi. 10.1002/ange.200600950
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Ein stabiles Silylenoid und ein Donor-stabilisiertes Chlorsilylen – niedrig koordinierte Siliciumverbindungen und kein Ende?
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4347, doi. 10.1002/ange.200601414
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Efforts towards Expansion of the Genetic Alphabet: Pyridone and Methyl Pyridone NucleobasesAcknowledgement for financial support is given to the National Institutes of Health (GM60005 to F.E.R.).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4432, doi. 10.1002/ange.200601272
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Vorschau: Angew. Chem. 26/2006.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4489, doi. 10.1002/ange.200690091
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Graphisches Inhaltsverzeichnis: Angew. Chem. 26/2006.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4328, doi. 10.1002/ange.200690090
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Titelbild: Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6] (Angew. Chem. 26/2006).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4325, doi. 10.1002/ange.200690089
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2-Thioindoles as Precursors to Spiro-Fused Indolines: Synthesis of (±)-DehaloperophoramidineThis research was supported by NIH General Medical Sciences (GM 61608) and the University of Utah. The authors thank Dr. Atta M. Arif, Dr. Charles L. Mayne, and Elliot M. Rachlin for help with the X-ray analysis, NMR spectroscopy, and mass spectrometry, respectively. Professor Chris M. Ireland is acknowledged for providing the spectral data of dehaloperophoramidine.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4423, doi. 10.1002/ange.200601278
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Significantly Improved Method for the Pd-Catalyzed Coupling of Phenols with Aryl Halides: Understanding Ligand EffectsWe thank the National Institutes of Health (GM 58160) for funding and Merck, Amgen, and Boehringer-Ingelheim for additional unrestricted support.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4427, doi. 10.1002/ange.200601253
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A 15-Vertex HeteroboraneThe chemistry described in this paper was part of presentation SP-B20 by R. D. McIntosh, K. J. Dalby, D. Ellis, M. E. Lopez, G. M. Rosair, A. J. Welch, and S. Zlatogorsky, at the 12th International Meeting on Boron Chemistry (IMEBORON-XII), Sendai, Japan, 15th September 2005. We thank the EPSRC and the Carnegie Trust for support, Dr. A. S. F. Boyd for NMR spectra, G. P. Smith for mass spectra, and C. Graham for microanalyses.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4419, doi. 10.1002/ange.200601266
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Struktur und Clusterbildung eines tert-ButylborylenkomplexesDiese Arbeit wurde von der Deutschen Forschungsgemeinschaft unterstützt. Wir danken der BASF AG für eine Chemikalienspende. H.B. dankt Prof. T. P. Fehlner (Notre Dame) für...
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4458, doi. 10.1002/ange.200601237
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Regiocontrol in MnIII-Mediated Oxidative Heterobicyclizations: Access to the Core Skeletons of Oroidin DimersWe gratefully acknowledge the Southwestern Medical Foundation and the Welch Foundation for financial support. We also thank Dr. Radha Akella for the X-ray analyses.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4451, doi. 10.1002/ange.200601208
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“Gyroskop-Giganten”: dipolare Cl-Rh-CO-Rotatoren, umgeben von Statoren aus drei Speichen 25- bis 27-gliedriger MakrocyclenWir danken der DFG (GL 300/1-3), der Alexander von Humboldt-Stiftung (Stipendium für L.W.) sowie Johnson...
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4479, doi. 10.1002/ange.200601191
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Organocatalytic Conjugate Addition of Malonates to α,β-Unsaturated Aldehydes: Asymmetric Formal Synthesis of (−)-Paroxetine, Chiral Lactams, and LactonesThis work was made possible by a grant from The Danish National Research Foundation. A.L. thanks Eusko Jaurlaritza/Gobierno Vasco for financial support (postdoctoral fellowship). J.F. thanks The Wenner–Gren Foundation for a grant. Thanks are expressed to Dr. Jacob Overgaard from the Department of Chemistry, Aarhus University for performing the X-ray crystal structure analysis.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4411, doi. 10.1002/ange.200601025
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[Rb([18]Krone-6)(NH3)3]Au⋅NH3: Gold als Acceptor in N—H⋅⋅⋅Au−-WasserstoffbrückenWir danken A. Müller für ihre Unterstützung bei den präparativen Arbeiten, Dr. J. Nuss...
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4476, doi. 10.1002/ange.200601093
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Sequence-Dependent Stereoselectivity in the Binding of Tetrapeptides in Water by a Flexible Artificial ReceptorWe thank the DFG (SFB 630) and the Fonds der Chemischen Industrie for ongoing financial support of our work.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4383, doi. 10.1002/ange.200601046
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Synthesis and Structure of 14- and 15-Vertex RuthenacarboranesThis work was supported by a grant from the Research Grants Council of the Hong Kong Special Administration Region (Project No. 403805) and a Strategic Investments Scheme administrated by The Chinese University of Hong Kong.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4415, doi. 10.1002/ange.200600890
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Asymmetric Synthesis of Chiral Aldehydes by Conjugate Additions with Bifunctional Organocatalysis by Cinchona AlkaloidsThis work was supported financially by the National Institutes of Health (GM-61591). We thank Stephen C. Wilson for his contribution to the studies described herein.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4407, doi. 10.1002/ange.200600867
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Assembly of Subnanometric 2D Pt Nanoislands in Parallel Rows onto Au(111) by Self-Organization of Pt ClustersFinancial support from MEC (MAT2005-06669-C03-02, NAN2004-09333-C05-04, MAT2005-07554-C02-01, and BQU 2005-03222) is gratefully acknowledged. O.G.V. acknowledges Cajacanarias, G.G. thanks the MEC for an FPI grant, and G.A.P. acknowledges MEC for a fellowship.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4372, doi. 10.1002/ange.200600826
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Site-Specific Protein Modification through CuI-Catalyzed 1,2,3-Triazole Formation and Its Implementation in Protein Microarray FabricationWe acknowledge financial support from the National Tsing Hua University (Academia Sinica Research Project on Nano Science and Technology) and the National Science Council, Taiwan.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4392, doi. 10.1002/ange.200600756
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Dynamic Covalently Bonded Rotaxanes Cross-Linked by Imine Bonds between the Axle and Ring: Inverse Temperature Dependence of Subunit MobilityWe are grateful to K. Watanabe of the GC-MS and NMR Laboratory (Hokkaido University) for the mass-spectrometric analyses and to Dr. Y. Kumaki of the High-Resolution NMR Laboratory (Hokkaido University) for the ROESY and variable-temperature NMR measurements. This study was supported by JSPS KAKENHI (No. 16750024).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4387, doi. 10.1002/ange.200600750
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Mixed Isotope Photoaffinity Reagents for Identification of Small-Molecule Targets by Mass SpectrometryWe thank M. Shortreed for assistance with the MS studies, and also M. Cancilla and A. Hegeman for insightful discussions. C.J.K. was supported by a Biotechnology Training Grant fellowship. This work was supported by generous financial support from the NIH (GM065406) and NHLBI (N01-HV-28182).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4435, doi. 10.1002/ange.200600743
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Crystallographic Analysis of Primary Visual PhotochemistryWe are grateful to H. Sakai and M. Kawamoto for excellent support at BL41XU of SPring-8, to T. Yoshizawa, Y. Shichida, M. Sakurai, E. M. Landau, and J. Navarro for critical reading of the early draft of the manuscript, and to M. Schreiber, M. Sugihara, and V. Buss for preparation of the manuscript. This research was supported in part by grants from MEXT (15687005) and by NEDO. The coordinate file of bathorhodopsin has been deposited with the Protein Data Bank (ID: 2G87).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4376, doi. 10.1002/ange.200600595
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Quantum Mechanical Studies on the Crystallographic Model of BathorhodopsinWe thank Dr. O. Weingart for helpful discussions. This research was supported in part by grants from MEXT (15687005), JST (CREST), NEDO, and the DFG (Forschergruppe FOR490).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4380, doi. 10.1002/ange.200600585
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A Ferrocenylspiropyran That Functions as a Molecular Photomemory with Controllable DepthThis work was supported by Grants-in-Aid for Scientific Research (nos. 16047204 (area 434) and 17205007), by a grant from The 21st Century COE Program for Frontiers in Fundamental Chemistry from MEXT, and by CREST, JST (Japan).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4404, doi. 10.1002/ange.200600535
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Geheimnisvolles PlatinnitridWir danken den Rechenzentren der RWTH Aachen und des Forschungszentrums Jülich für die Bereitstellung von Rechenkapazität. Für finanzielle Unterstützung danken wir der Deutschen...
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4472
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Anisotropic Movements of Coordination Polymers upon Desolvation: Solid-State Transformation of a Linear 1D Coordination Polymer to a Ladderlike StructureThe National University of Singapore is thanked for its generous funding of this project. We thank Prof. L. L. Koh for his help with X-ray crystallography.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4443
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Universelle Tinte für den MikrokontaktdruckWir danken J. H. M. Snijders für die Durchführung von XPS-Analysen, H. A. G. Nulens für AFM-Analysen und G. L. T. van den Heuvel für die Unterstützung in der Analytik....
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4461, doi. 10.1002/ange.200600310
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Higher-Nuclearity Group 14 Metalloid Clusters: [Sn9{Sn(NRR′)}6]We thank the EPSRC (A.V.P.) and the Royal Society (A.R.) for postdoctoral fellowships and the CRC Program of the U.S. National Science Foundation for financial support. R=2,6-iPr2C6H3; R′=SiMe3 or SiMe2Ph.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4439, doi. 10.1002/ange.200600292
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Ein Heterofulven-analoges Germylen mit Betain-Reaktivität.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4455, doi. 10.1002/ange.200600237
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A Self-Complementary Assembly of Metallamacrocycles Directed by Ru—Cl⋅⋅⋅H—N Hydrogen Bonds and Its Reversible Dichotomy by Halide Anions in SolutionThis work was supported by the Korean Science and Engineering Foundation (KOSEF; Grant No. R01-2001-00053). We thank the Center for Bioactive Molecular Hybrids for their support for H.-s.P. and Yong Joo Jun for his help with the 31P NMR spectroscopic measurements.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4396, doi. 10.1002/ange.200600154
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Chemistry of Peptide Synthesis. Von N. Leo Benoiton.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4340, doi. 10.1002/ange.200585369
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Schaltbare Hydrogele durch supramolekulare Vernetzung adamantylhaltiger LCST-Copolymere mit Cyclodextrin-DimerenLCST=untere kritische Entmischungstemperatur (lower critical solution temperature).
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4468, doi. 10.1002/ange.200504539
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Einfache Bildung eines beständigen Butadien-2-yl-Kations: Stabilisierung durch Hyperkonjugation mit einer Al-C-BindungDiese Arbeit wurde von der Deutschen Forschungsgemeinschaft und dem Fonds der Chemischen Industrie gefördert. Wir danken...
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4465, doi. 10.1002/ange.200504428
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Sequenzielle Eintopfreaktionen mithilfe isolierter aktiver Zentren.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4344, doi. 10.1002/ange.200504353
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Der Weg zur Struktur amorpher Festkörper – eine Studie am Beispiel der Keramik Si3B3N7.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4350, doi. 10.1002/ange.200504193
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Synthesis and Characterization of Mesoporous Silica AMS-10 with Bicontinuous Cubic Pn$\bar 3$m SymmetryThis work was supported by the National Natural Science Foundation of China (grant no. 20425102 and 20521140450), the China Ministry of Education, and the Shanghai Science Foundation (0452nm061 and 05XD14010). O.T. thanks the Swedish Science Research Council (VR) and Japan Science and Technology Agency (JST) for financial support.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4401, doi. 10.1002/ange.200504114
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Candid Science IV. Conversations with Famous Physicists. Von Magdolna Hargittai und István Hargittai.
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- Angewandte Chemie, 2006, v. 118, n. 26, p. 4341, doi. 10.1002/ange.200485395
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