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- Title
Synthesis of 1‐amino‐3‐aryl Naphthalenes from Bis(perfluoroalkanesulfonyl)imide with 1,2‐diethynylbenzenes.
- Authors
Kawamoto, Takuji; Yamasaki, Tetsushi; Ikazaki, Tsubasa; Matsubara, Hiroshi; Kamimura, Akio
- Abstract
Although the synthesis of vinyl triflates has a long history, the synthesis of vinyl bis(perfluoroalkanesulfonyl)imides has not been reported yet. Here, we report a simple synthetic route to vinyl bis(perfluoroalkanesulfonyl)imides that does not require any additives. The stereoselectivity originates from the steric hindrance between the aryl group and the imide. The reaction proceeds chemoselectively, and subsequent cyclization provides the 1‐amino‐3‐aryl naphthalene derivatives.
- Subjects
NAPHTHALENE; STERIC hindrance; ARYL group; NAPHTHALENE derivatives; IMIDES; CHEMOSELECTIVITY
- Publication
Asian Journal of Organic Chemistry, 2024, Vol 13, Issue 5, p1
- ISSN
2193-5807
- Publication type
Academic Journal
- DOI
10.1002/ajoc.202400035