Title: Highly N<sup>2</sup>-Regioselective TsOH-Catalyzed Olefin Hydroamination: Metal-Free Synthesis of N<sup>2</sup>-Alkyl-1,2,3-triazoles.
Authors: Wei, Hao; Hu, Qingxia; Ma, Yutao; Wei, Liangming; Liu, Jiaqiang; Shi, Min; Wang, Feijun
Abstract: A highly N2-regioselective functionalization of 2 H-1,2,3-triazole and 1 H-1,2,3-triazole was achieved via a para-toluenesulfonic-acid-catalyzed olefin hydroamination. The reaction afforded the corresponding products with up to 92 % N2 regioselectivity.
Subjects: NITROGEN compounds; REGIOSELECTIVITY (Chemistry); HYDROAMINATION
Publication: Asian Journal of Organic Chemistry, 2017, Vol 6, Issue 6, p662
ISSN: 2193-5807
Publication type: Academic Journal
DOI: 10.1002/ajoc.201700045

Highly N<sup>2</sup>-Regioselective TsOH-Catalyzed Olefin Hydroamination: Metal-Free Synthesis of N<sup>2</sup>-Alkyl-1,2,3-triazoles.

Wei, Hao; Hu, Qingxia; Ma, Yutao; Wei, Liangming; Liu, Jiaqiang; Shi, Min; Wang, Feijun