Highly Air‐Stable Single‐Crystalline β‐CsPbI₃ Nanorods: A Platform for Inverted Perovskite Solar Cells.

Mahato, Somnath; Ghorai, Arup; Srivastava, Sanjeev Kumar; Modak, Mantu; Singh, Sudarshan; Ray, Samit K.

The synthesis of single‐crystalline β‐CsPbI3 perovskite nanorods (NRs) using a colloidal process is reported, exhibiting their improved photostability under 45–55% humidity. The crystal structure of CsPbI3 NRs films is investigated using Rietveld refined X‐ray diffraction (XRD) patterns to determine crystallographic parameters and the phase transformation from orthorhombic (γ‐CsPbI3) to tetragonal (β‐CsPbI3) on annealing at 150 °C. Atomic resolution transmission electron microscopy images are utilized to determine the probable atomic distribution of Cs, Pb, and I atoms in a single β‐phase CsPbI3 NR, in agreement with the XRD structure and selected area electron diffraction pattern, indicating the growth of single crystalline β‐CsPbI3 NR. The calculation of the electronic band structure of tetragonal β‐CsPbI3 using density functional theory (DFT) reveals a direct transition with a lower band gap and a higher absorption coefficient in the solar spectrum, as compared to its γ‐phase. An air‐stable (45–55% humidity) inverted perovskite solar cell, employing β‐CsPbI3 NRs without any encapsulation, yields an efficiency of 7.3% with 78% enhancement over the γ‐phase, showing its potential for future low cost photovoltaic devices.

SOLAR cells; SILICON solar cells; BAND gaps; ELECTRONIC band structure; PEROVSKITE; NANORODS

Advanced Energy Materials, 2020, Vol 10, Issue 30, p1

1614-6832

Academic Journal

10.1002/aenm.202001305