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Graphical Abstract: Angew. Chem. Int. Ed. 25/2006.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4040, doi. 10.1002/anie.200690087
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Preview: Angew. Chem. Int. Ed. 25/2006.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4217, doi. 10.1002/anie.200690088
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Master Mind. The Rise and Fall of Fritz Haber. By Daniel Charles.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4053, doi. 10.1002/anie.200585375
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Biochemistry: R. R. Breaker honored / / Organic Chemistry: D. W. C. MacMillan awarded / / Biochemistry: Prize to J. K. Barton.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4052, doi. 10.1002/anie.200601982
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Electrodeposition of Silver Particles and Gold Nanoparticles from Ionic Liquid-Crystal PrecursorsWe are especially grateful to Dr. J. Harrowfield for the critical evaluation of the manuscript. We also thank A. De Cian and B. Heinrich for the X-ray diffraction studies, and J. Faerber for the scanning electron micrographs. This work was supported by the Institut de Physique et Chimie des Matériaux de Strasbourg, the Université Louis Pasteur, and NANORGYSOL A.N.R.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4179, doi. 10.1002/anie.200600929
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Chiral BorromeatesThe research at UCLA was supported by the National Science Foundation (NSF).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4099, doi. 10.1002/anie.200600817
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The Heck Reaction of Electron-Rich Olefins with Regiocontrol by Hydrogen-Bond Donors.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4152, doi. 10.1002/anie.200600799
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Cover Picture: Chiral Borromeates (Angew. Chem. Int. Ed. 25/2006).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4037, doi. 10.1002/anie.200690086
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Radical Photochemistry in Oxygen-Loaded Ices.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4159, doi. 10.1002/anie.200504509
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A Snapshot of P4 Tetrahedron Opening: Rh- and Ir-Mediated Activation of White PhosphorusThe stay of D.Y. in Florence was supported by the INTAS YS fellowship program 2003 (Fellowship Ref. Nr. 03-55-2050). S.M.C. thanks the “Ministerio de Ciencia y Tecnologia” (Spain) for a postdoctoral grant. Thanks are due to Thermphos Int. (Vlissingen, Netherlands) for a generous loan of white phosphorus, to the NMR service of “FIRENZE HYDROLAB”, a project sponsored by Ente Cassa di Risparmio di Firenze, and to Dr. A. Raffaelli (ICCOM CNR, Pisa) for running the ESI-MS spectrum of 5-OTf.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4182, doi. 10.1002/anie.200601048
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Self-Supported and Clean One-Step Cathodic Coupling of Activated Olefins with Benzyl Bromide Derivatives in a Micro Flow ReactorWe thank the EPSRC for funding.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4146, doi. 10.1002/anie.200600951
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The Potential of a cyclo-As3-Ligand Complex in Supramolecular ChemistryThis work was comprehensively supported by the Deutsche Forschungsgemeinschaft and the Fonds der Chemischen Industrie. M. Sierka gratefully acknowledges Prof. Joachim Sauer and the Humboldt-Universität zu Berlin for providing computing facilities.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4189, doi. 10.1002/anie.200600815
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Supramolecular Chirality in Layered Crystals of Achiral Ammonium Salts and Fatty Acids: A Hierarchical InterpretationA.T. expresses his special thanks to the Center of Excellence (21COE) program “Creation of Integrated EcoChemistry of Osaka University”. This work was also supported by a Grant-in-Aid for Scientific Research (15350070) from the Ministry of Education, Culture, Sports, Science, and Technology, Japan.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4142, doi. 10.1002/anie.200504424
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From Aryl Bromides to Enantioenriched Benzylic Alcohols in a Single Flask: Catalytic Asymmetric Arylation of AldehydesWe thank the National Institutes of Health (National Institute of General Medical Sciences) and the National Science Foundation for support of this research.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4175, doi. 10.1002/anie.200600741
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Pericyclic Cascade Reactions of (Bicyclo[1.1.0]butylmethyl)aminesThis work was supported by the National Science Foundation (CHE-0315205). We thank Dr. Steve Geib for the X-ray crystallographic analysis and Juan Arredondo for help with the acquisition of the NMR spectra.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4172, doi. 10.1002/anie.200600723
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Progressive Stabilization of Zwitterionic Structures in [H(Ser)2–8]+ Studied by Infrared Photodissociation SpectroscopyThis study was supported by the Academia Sinica and the National Science Council (Grant No. NSC 92-3112-B-001-012-Y under the National Research Program for Genomic Medicine) of Taiwan, Republic of China. We thank Professors O. P. Charkin, H. B. Oh, and F. W. McLafferty for insightful discussions.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4130, doi. 10.1002/anie.200600597
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High-Nuclearity, High-Symmetry, High-Spin Molecules: A Mixed-Valence Mn10 Cage Possessing Rare T symmetry and an S=22 Ground StateThis work was supported by the U.S. National Science Foundation (Grant CHE-0414155).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4134
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Solid-Phase Oligosaccharide Tagging (SPOT): Validation on Glycolipid-Derived StructuresThis work was supported by the Danish Technical Research Council (STVF).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4167, doi. 10.1002/anie.200600642
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Fundamental Processes in Radiation Damage of DNA.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4056, doi. 10.1002/anie.200600614
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Chemical Composition and Topology of Poly(lactide-co-glycolide) Revealed by Pushing MALDI-TOF MS to Its LimitThe authors thank SenterNovem and Dolphys Medical for financial support and the Foundation of Emulsion Polymerization (SEP) for the use of the MALDI-TOF MS equipment.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4104, doi. 10.1002/anie.200600594
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An Optically Reversible Switching Membrane SurfaceWe acknowledge the support of the US Department of Energy (Grant No. DE-FG02-90ER14114) and the National Science Foundation (Grant No. CTS-94-00610).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4094, doi. 10.1002/anie.200600581
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Building Complex Glycopeptides: Development of a Cysteine-Free Native Chemical Ligation ProtocolThis work was supported by the National Institutes of Health (Grant CA28824 to S.J.D., and CA62948 to J.D.W.) and by New York State Department of Health, New York State Breast Cancer Research and Education Fund (to B.W.).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4116, doi. 10.1002/anie.200600538
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DNA-Templated Synthesis in Three Dimensions: Introducing a Micellar Scaffold for Organic ReactionsThis work, as part of the European Science Foundation EUROCORES Programme BIONICS, was supported by funds from the DFG and the EC Sixth Framework Programme. Additional funding was provided through the ERA-CHEMISRY Programme. The help of Dr. Roland Bauer for creating graphical representations is gratefully acknowledged. We also thank Prof. Hans-Jürgen Butt for his support.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4206, doi. 10.1002/anie.200600524
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Highly Stereoselective Synthesis of TMS-, Alkyl-, or Aryl-Substituted cis-[3]Cumulenols via α-Alkynylated ZirconacyclopentenesTMS=trimethylsilyl. We thank the National Natural Science Foundation of China, the Chinese Academy of Science, and the Science and Technology Commission of Shanghai Municipality (grant no.: 04QMX1446) for financial support. We also thank Prof. Tamotsu Takahashi for his helpful discussions.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4163, doi. 10.1002/anie.200600520
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Asymmetric Counteranion-Directed CatalysisTechnical assistance by Simone Marcus, Jutta Rosentreter, Michael Stadler, and Dr. Jung Woon Yang is gratefully acknowledged. We thank the Max-Planck Institut, Degussa, Lanxess, and Wacker for support of our work, the Deutsche Forschungsgemeneinschaft for the priority program “Organocatalysis” (SPP 1179), and Novartis for a Young Investigator Award.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4193, doi. 10.1002/anie.200600512
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Mechanism of the Vinylcyclobutane Rearrangement of Sceptrin to Ageliferin and Nagelamide EWe thank Dr. D. H. Huang and Dr. L. Pasternack for assistance with the NMR spectroscopy; Biotage for a generous donation of microwave process vials, which were used extensively during these studies; and the Department of Defense and the Hertz Foundation for pre-doctoral fellowships (D.P.O.). Financial support for this work was provided by The Scripps Research Institute, Amgen, Dupont, Eli Lilly, GlaxoSmithKline, Roche, the Searle Scholarship Fund, NIH/NIGMS (GM-073949 to P.S.B), the National Science Foundation (research grant CHE-0240203 to K.N.H), and IGERT (a (MCTP)-DGE-0114443 fellowship to B.H.N.).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4126, doi. 10.1002/anie.200600514
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Biaryl Axis as a Stereochemical Relay for the Enantioselective Synthesis of Antimicrotubule Agents We thank M.-E. Tran Huu Dau for the AM1 calculations, F. Guéritte and D. Guénard for support, and E. Bacqué for a useful suggestion. This work was financially supported by the ICSN-CNRS.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4149, doi. 10.1002/anie.200600451
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Engineering a Polymeric Chiral Catalyst by Using Hydrogen Bonding and Coordination InteractionsFinancial support from the National Natural Science Foundation of China, the Chinese Academy of Sciences, the Major Basic Research Development Program of China (grant no. G2000077506), and the Ministry of Science and Technology of Shanghai Municipality is gratefully acknowledged.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4108, doi. 10.1002/anie.200600432
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Adhesion of a Free-Standing Newton Black Film onto a Solid SubstrateWe thank Prof. Ichinose and Dr. Jin of the NIMS (Japan) for fruitful discussions on the formation of black films. We also acknowledge financial support from the France/Hong Kong Joint Research Scheme F-HK20/03T.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4186, doi. 10.1002/anie.200600367
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Formation of Zirconocene Fluoro Complexes: No Deactivation in the Polymerization of Olefins by the Contact-Ion-Pair Catalysts [Cp′2ZrR]+[RB(C6F5)3]−We are grateful to the Deutsche Forschungsgemeinschaft (Research Training Group 1213 and SPP 1118, project no. RO 1269/6) and the Russian Foundation for Basic Research (project code 05-03-32515) for financial support. We thank our technical staff, in particular Petra Bartels and Regina Jesse, for skilled assistance. Cp′=substituted or unsubstituted η5-cyclopentadienyl; R=Me, H.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4195, doi. 10.1002/anie.200600361
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Nanochannel-Promoted Polymerization of Substituted Acetylenes in Porous Coordination PolymersWe thank Prof. Y. Chujo of Kyoto University for access to GPC apparatus. This work was supported by a Grant-in-Aid for Scientific Research in a Priority Area “Chemistry of Coordination Space” (no. 434) and a Grant-in-Aid for Young Scientists (B; no. 17750125) from the Ministry of Education, Culture, Sports, Science and Technology, Government of Japan.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4112, doi. 10.1002/anie.200600333
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[{(tBu2Me)2Si}3Li4]2−: An Aggregated Dianion of a 1,1-Dilithiosilane with a Unique Structural MotifThis research was supported by the Israel Science Foundation administrated by the Israel Academy of Sciences and Humanities, the Fund for the Promotion of Research at the Technion, and the Minerva Foundation in Munich. M.B. and D.B.-Z. are grateful to the Ministry of Immigrant Absorption, State of Israel for a Kamea scholarship. The authors thank Dr. Yael Balazs for helpful discussions and technical assistance.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4157, doi. 10.1002/anie.200600308
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Fluorine in a Native Protein Environment—How the Spatial Demand and Polarity of Fluoroalkyl Groups Affect Protein FoldingThis work was supported by the Deutsche Forschungsgemeinschaft (KO1976/2-1) and the Graduiertenkolleg (#788).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4198
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Liquid Crystals from C3-Symmetric Mesogens for Second-Order Nonlinear OpticsThis work was supported by the MEC, Spain (BQU2000–0226 and Ramón y Cajal contract for G.H.), the CICYT of Spain, the FEDER funds (EU, project MAT2003-07806-C01), and by the Diputación General de Aragón, as well as by the University of Leuven (GOA/2006/03), the Institute for the Promotion of Innovation through Science and Technology in Flanders (IWT-Vlaanderen), the FWO-V (G.0297.04), and the Belgian government (IUAP/5). I.A. acknowledges a fellowship from the Flemish Fund for Scientific Research. (FWO-V).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4203, doi. 10.1002/anie.200600019
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Accelerated Discovery of Red-Phosphorescent Emitters through Combinatorial Organometallic Synthesis and ScreeningThe authors are grateful to the National Science Council, ROC, for financial support of this work (grant NSC 93-2113-M-008-009). We are also thankful to Chitec Technology Co., Ltd. for supplying electroluminescent device testing data.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4138, doi. 10.1002/anie.200600004
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Some Experimental Evidence that Zn4O(BO3)2 is Zn6O(OH)(BO3)3.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4060, doi. 10.1002/anie.200503999
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Biomolecular Modeling: Goals, Problems, Perspectives.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 25, p. 4064, doi. 10.1002/anie.200502655
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