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Synthesis of Macrocyclic Poly(ɛ-caprolactone) by Intramolecular Cross-Linking of Unsaturated End Groups of Chains Precyclic by the InitiationThe authors are much indebted to the “Belgian Science Policy” for financial support and a fellowship to H.L. in the frame of the “Interuniversity Attraction Poles” Programme (PAI V/03): Supramolecular Chemistry and Supramolecular Catalysis. P.L. is research associate with the Belgian “Fonds National de la Rechecherche Scientifique”.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2264, doi. 10.1002/anie.200503961
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Diagnostics of Single Base-Mismatch DNA Hybridization on Gold Nanoparticles by Using the Hyper-Rayleigh Scattering Technique.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2162, doi. 10.1002/anie.200690052
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Preview: Angew. Chem. Int. Ed. 14/2006.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2313, doi. 10.1002/anie.200690051
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Reaction Progress Kinetic Analysis: A Powerful Methodology for Mechanistic Studies of Complex Catalytic Reactions.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2162, doi. 10.1002/anie.200690050
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Graphical Abstract: Angew. Chem. Int. Ed. 14/2006.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2152, doi. 10.1002/anie.200690049
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Organisilicon Chemistry VI. From Molecules to Materials. Edited by Norbert Auner and Johann Weis.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2166, doi. 10.1002/anie.200585345
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Autonomous Fueled Mechanical Replication of Nucleic Acid Templates for the Amplified Optical Detection of DNAThis research was supported by the Israel Ministry of Science as an Infrastructure Project.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2238, doi. 10.1002/anie.200503810
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Low-Surface-Free-Energy Materials Based on Polybenzoxazines.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2248, doi. 10.1002/anie.200503957
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Regio- and Stereoselective Decarbonylative Carbostannylation of Alkynes Catalyzed by Pd/CThis work was supported financially by Grant-in-Aids for Creative Scientific Research (No. 16GS0209) and COE Research on “Elements Science” and on a “United Approach to New Material Science” from MEXT.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2271, doi. 10.1002/anie.200504283
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Cover Picture: Autonomous Fueled Mechanical Replication of Nucleic Acid Templates for the Amplified Optical Detection of DNA (Angew. Chem. Int. Ed. 14/2006).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2149, doi. 10.1002/anie.200690048
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/ Chemoinformatics: Prize to J. Gasteiger / Organometallic Chemistry: J. F. Hartwig Honored / Biochemistry: P. G. Schultz Awarded.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2164, doi. 10.1002/anie.200600728
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Handbook of C-H Transformations. Applications in Organic Synthesis. Edited by Gerald Dyker.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2165, doi. 10.1002/anie.200585357
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Highly Diastereoselective One-Pot Synthesis of Spirocyclic Oxindoles through Intramolecular Ullmann Coupling and Claisen RearrangementWe thank Professor Takao Ikariya and Professor Shigeki Kuwata (Tokyo Institute of Technology) for X-ray crystallographic analysis. We also thank Shin-Etsu Chemical Co. Ltd. for a gift of silicone oil.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2274, doi. 10.1002/anie.200504247
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Nanoparticle-Assisted Visualization of Binding Interactions between Collagen Mimetic Peptide and Collagen FibersThis work was supported by the NSF (CTS-0210220) and the NIH (GM-74812).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2267, doi. 10.1002/anie.200504529
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Isolation of a 1,2-DialuminacyclobuteneThis work was supported by the National Natural Science Foundation of China (20421202) and the NCET.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2245, doi. 10.1002/anie.200504329
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Annulative Tandem Reactions Based on Pd0/tBu3P-Catalyzed Cross-Coupling and C(sp3)—H Bond ActivationWe thank the NIH (GM69704) for funding. Partial support from the PSC-CUNY Research Award Program is gratefully acknowledged. We thank Ms. Hui-Yu Liu and Ms. Anna P. Yeung for some experimental work, Prof. Shuiqin Zhou for helpful discussions, and Prof. Alec Greer for help with the GCMS analysis.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2289, doi. 10.1002/anie.200504310
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Efficient Phenanthrene, Helicene, and Azahelicene SynthesesFinancial support from the EPSRC through the Doctoral Training Account is gratefully acknowledged.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2242, doi. 10.1002/anie.200504287
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Imaging Proteins in Membranes of Living Cells by High-Resolution Scanning Ion Conductance MicroscopyThis work was funded by the Biotechnology and Biological Sciences Research Council (UK). The development of the high-resolution scanning ion conductance microscopy instrument was performed in collaboration with Ionscope Limited (UK).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2212, doi. 10.1002/anie.200503915
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Organocatalytic Enantioselective Photoreactions.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2168, doi. 10.1002/anie.200503908
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Synthesis of a “Half”-Parent Phosphasilene R2Si=PH and Its Metalation to the Corresponding P-Zinciophosphasilene [R2Si=PM]M={Zn(tmeda)Me}; tmeda=N,N,N′,N′-tetramethylethylenediamine.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2293, doi. 10.1002/anie.200504145
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Synthesis of Stable Super Water- and Oil-Repellent Polythiophene Films.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2251, doi. 10.1002/anie.200503892
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Catalytic Activation of N—N Multiple Bonds: A Homogeneous Palladium Catalyst for Mechanistically Unprecedented Reduction of Azo CompoundsThis work was supported by the Université Louis Pasteur and by the Fonds der Chemischen Industrie. K.M. thanks Prof. J.-M. Lehn for providing temporary laboratory space at the Institut de Science et d'Ingénierie Supramoléculaires (ISIS).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2305, doi. 10.1002/anie.200503875
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An Unprecedented Example of a Hetero-trimetallic Main-Group [L2Al2Ge4Li2S7] Cluster Containing a GeII—GeII Donor–Acceptor BondThis work was supported by the Fonds der Chemischen Industrie and the Göttinger Akademie der Wissenschaften. L=HC(CMeNAr)2, Ar=2,6-iPr2C6H3.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2277, doi. 10.1002/anie.200503940
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Construction of Asymmetric Fluorinated Carbon Centers.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2172, doi. 10.1002/anie.200503783
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Nonribosomal Peptide Biosynthesis: Point Mutations and Module Skipping Lead to Chemical DiversityThe authors would like to thank B. Arbogast and L. Barofsky (Mass Spectrometry Core of the Environmental Health Sciences Center, Oregon State University, NIH grant P30 ES00210) for the ESI/ICR and MALDI-TOF analysis and B. Hinkelmann and H. Schüler for performing a large-scale fermentation. We are also grateful to Prof. Dr. T. M. Zabriskie, Dr. H. B. Bode, and B. Lelarge for the critical review of this manuscript. This work was supported by grants from the BMB+F and the DFG. S.C.W. and R.M. would like to acknowledge a Kekulé fellowship of the Fonds der Chemischen Industrie and a DAAD fellowship.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2296, doi. 10.1002/anie.200503737
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Asymmetric Retro-[1,4] Brook Rearrangement and Its Stereochemical Course at SiliconThis research was supported by a Grant-in-Aid for Scientific Research on Priority Areas (A) “Creation of Biologically Functional Molecules”, Basic Area (B) No. 14350473, Exploratory Research No. 17655038, and the 21st Century COE Program “Creation of Molecular Diversity and Development of Functionalities” from the Ministry of Education, Culture, Sports, Science, and Technology, Japan. The authors thank Dr. Kazunobu Igawa and Tomohiro Shimono for helpful discussions and technical assistance.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2235, doi. 10.1002/anie.200503734
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A Subtle End-Group Effect on Macroscopic Physical Gelation of Triblock Copolymer Aqueous SolutionsWe are grateful for the financial support from the NSF of China (20 374 015, 50 533 010, and 20 574 013), the Key Grant of the Chinese Ministry of Education (305 004), 973 Project and 863 Project (2005CB522700) from the Chinese Ministry of Science and Technology, and the Science and Technology Developing Foundation of Shanghai (04JC14019 and 055 207 082).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2232, doi. 10.1002/anie.200503575
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Synthesis of Macrocyclic Aluminum–Phosphorus and Gallium–Phosphorus CompoundsThe authors thank Dr. E. Matern for his help with the NMR experiments.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2302, doi. 10.1002/anie.200503531
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High Substrate/Catalyst Organocatalysis by a Chiral Brønsted Acid for an Enantioselective Aza-Ene-Type ReactionThis work was partially supported by a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Sports, Science and Technology, Japan, and The Tokuyama Science Foundation.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2254, doi. 10.1002/anie.200503477
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Expanding the Utility of One-Pot Multistep Reaction Networks through Compartmentation and Recovery of the CatalystThe US DOE Office of Basic Energy Sciences is acknowledged for financial support through Catalysis Science Contract No. DE-FG02-03ER15459. DuPont is also thanked for a Young Professor Award. C.W.J. acknowledges support from ChBE at GT through the J. Carl & Sheila Pirkle Faculty Fellowship.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2209, doi. 10.1002/anie.200503445
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A Caged Doxycycline Analogue for Photoactivated Gene ExpressionWe thank T. Bonhoeffer for continued support of this project; P. Schmieder (FMP) and E. Krause (FMP) for the NMR spectroscopic and mass-spectrometric analysis, respectively; R. Scholz for help with the photoactivation of the tobacco leafs (in the laboratory of C. Gatz); B. Schwappach for providing the Chinese hamster ovary cells; and T. Bonhoeffer, V. Hagen, and V. Stein for critical reading of the manuscript. This study was supported by the Max-Planck society; a DFG fellowship (B.C.); a Volkswagen-Stiftung grant, a Minorities in Neuroscience Fellowship Program, and a Schloessmann Fellowship (S.B.C.); and the European Commission (grant no. QLK3-CT-2002-01989; S.K.).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2229, doi. 10.1002/anie.200503339
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On the Issue of the Deactivation of Au–Ceria and Pt–Ceria Water–Gas Shift Catalysts in Practical Fuel-Cell ApplicationsThis work was supported by the National Science Foundation, NIRT (Grant 0304515), and the Department of Energy, Basic Energy Sciences, Hydrogen Fuel Initiative (Grant DE-FG02-05ER15730).
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2285, doi. 10.1002/anie.200503220
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DNA Sequencing Based on Intrinsic Molecular ChargesWe thank Dr. Y. Horiike, Dr. J. Tanaka, Dr. H. Otsuka, and A. Ueda of the National Institute for Materials Science, Japan, Y. Nakajima of Ryokusei M.E.S. Co., Ltd., Japan, M. Kamahori of Hitachi Ltd., Japan, and Dr. P. Fortina of Thomas Jefferson University, USA, for their help and useful discussions.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2225, doi. 10.1002/anie.200503154
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Asymmetric Hydrogenation of Quinolines and Isoquinolines Activated by ChloroformatesWe are grateful for the financial support from the National Science Foundation of China and Dalian Institute of Chemical Physics (K2004Eo3), Chinese Academy of Sciences.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2260, doi. 10.1002/anie.200503073
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Label-Free Affinity Assays by Rapid Detection of Immune Complexes in Submicrometer PoresThis work was supported by an NSF CAREER award (M.M.) and by a research grant from IMRA America and AISIN USA as well as seed funds from the College of Engineering, University of Michigan. The authors thank Daniel J. Estes, Amy P. Wong, Irina Gitlin, and Paul Bina for valuable discussions.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2281, doi. 10.1002/anie.200502862
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Ab Initio MO Analysis of the Excited Electronic States of High-Spin Quintet 2-Methylphenylene-1,3-dinitreneThis work has been supported by Grants-in-Aid for Scientific Research from the Ministry of Education, Sports, Culture, Science and Technology, Japan.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2257, doi. 10.1002/anie.200502695
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Sequential Self-Assembly of a DNA Hexagon as a Template for the Organization of Gold NanoparticlesThis work was supported by the NSERC, the Canada Foundation for Innovation, Nanoquebec, Research Corporation, the Center for Self-Assembled Chemical Structures, and the NSERC Strategic Grant Program. We thank Antisar R. Hlil for MALDI-TOF MS measurements. H.F.S. is a Cottrell Scholar of the Research Corporation.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2204, doi. 10.1002/anie.200502481
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Magnetic Behavior of a 1D Molecular-Oxygen System Included within a Transformable Single-Crystal AdsorbentThis work was financially supported by the Ministry of Education, Culture, Sports, Science and Technology, Japan (Nos. 16750051 and 17036056) and a grant for the 2005 Strategic Research Project (No. K17025) of Yokohama City University.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2216, doi. 10.1002/anie.200501639
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Metal Vinylidenes and Allenylidenes in Catalysis: Applications in Anti-Markovnikov Additions to Terminal Alkynes and Alkene Metathesis.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2176, doi. 10.1002/anie.200501391
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Colloidal CdSe Nanocrystals Passivated by a Dye-Labeled Multidentate Polymer: Quantitative Analysis by Size-Exclusion ChromatographyThe authors thank NSERC Canada for their support of this research. G.D.S. acknowledges the A. P. Sloan Foundation. We thank Dr. M. A. Hines for the kind gift of ZnSe samples. We acknowledge helpful discussions with Dr. X.-S. Wang and Dr. Z. Yin, as well as the help of Mr. Y. Wang, Dr. N. Coombs, and Dr. M. Mamak for the TEM measurements.
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- Angewandte Chemie International Edition, 2006, v. 45, n. 14, p. 2221, doi. 10.1002/anie.200502538
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