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Linear free energy relationship and kinetic isotope effects as measures for the transition-state variation — A case of the neophyl system.
- Published in:
- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1606, doi. 10.1139/V05-209
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- Article
The fragmentation of 7-norbornyloxychlorocarbene — S<sub>N</sub>i-like transition states.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1228, doi. 10.1139/V05-118
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- Article
Kinetics and mechanism of the oxidation of alcohols by tetrapropylammonium perruthenate.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1212, doi. 10.1139/V05-114
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- Article
Kinetics and mechanism of acid-catalyzed hydrolysis of the diazo functional groups of 1-diazo-2-indanone and 2-diazo-1-indanone in aqueous solution.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1202, doi. 10.1139/V05-115
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- Article
The remarkable effect of 7-amino substituents on the reactivity of 4-nitrobenzofurazans with nucleophiles.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1222, doi. 10.1139/V05-116
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- Article
The structure, photochemical reactivity, and photophysical properties of adamantyl X-substituted aryl ethers and a comparison with the alkyl groups, methyl, tert-butyl, and allyl.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1237, doi. 10.1139/V05-117
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- Article
Acceleration of the methanolysis of phosphate diesters promoted by La(OTf)<sub>3</sub> — The analysis of non-integer.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1268, doi. 10.1139/V05-065
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- Article
Kinetics of glycoluril template-directed Claisen condensations — Effect of thionation of the glycoluril.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1253, doi. 10.1139/V05-119
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- Article
The art of discovery in biophysical organic chemistry.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1207, doi. 10.1139/V05-120
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- Article
Ambident reactivity of phenoxyl radicals in DNA adduction.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1261, doi. 10.1139/V05-121
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- Article
The aromatic character and resonance stabilization energies of substituted cyclopentadienyl and indenyl cations.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1287, doi. 10.1139/V05-137
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- Article
Solvolysis and ring closure of quinone methides photogenerated from biaryl systems.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1306, doi. 10.1139/V05-138
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- Article
Photochemical generation and <sup>1</sup>H NMR detection of alkyl allene oxides in solution.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1347, doi. 10.1139/V05-139
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- Article
Kinetic isotope effect evidence for the concerted transfer of hydride and proton from hydroxycyclopentadienyl ruthenium hydride in solvents of different polarities and hydrogen bonding ability.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1339, doi. 10.1139/V05-140
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- Article
An ab initio study of 1,5-suprafacial shifts in 5-substituted 1,3-cyclopentadienes.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1299, doi. 10.1139/V05-141
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- Article
A comparison of the mechanisms of hydrolysis of benzimidates, esters, and amides in sulfuric acid media.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1391, doi. 10.1139/V05-142
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- Article
The HERON reaction — Origin, theoretical background, and prevalence.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1492, doi. 10.1139/V05-150
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- Article
Bicyclo[3.2.0]hepta-1,3,6-triene — UV photoelectron spectroscopic and computational studies.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1352, doi. 10.1139/V05-145
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- Article
Reactions of acetoxy(methylthio)carbene and S-methyl thiopyruvate.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1360, doi. 10.1139/V05-151
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- Article
Photochemistry of 9-methylbicyclo[3.3.1]nonyl aryl ketones — A novel 1,5-disproportionation of 1,4-hydroxy biradicals and asymmetric induction using the solid-state ionic chiral auxiliary method.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1460, doi. 10.1139/V05-147
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- Article
Time-resolved spectroscopic studies of the photochemistry of some diphenylgermylene (Ph<sub>2</sub>Ge:) precursors.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1324, doi. 10.1139/V05-148
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- Article
Hydrolysis of aryl hydrogen maleate esters mediated by cyclodextrins — Effect on the intramolecular catalysis.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1281, doi. 10.1139/V05-144
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- Article
Computational studies of the properties of phenyloxenium ions — A comparison with phenylnitrenium and phenylcarbenium ions.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1372, doi. 10.1139/V05-149
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- Article
Deuterium labeling as a test of intramolecular hydride mechanisms in the fragmentation of 2-(1-hydroxybenzyl)-N1′-methylthiamin.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1277, doi. 10.1139/V05-146
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- Article
Pople, Schneider, and Bernstein — A truly seminal treatise of NMR.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1626, doi. 10.1139/V05-156
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- Article
Competitive endo- and exo-cyclic C–N fission in the hydrolysis of N-aroyl β-lactams.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1432, doi. 10.1139/V05-153
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- Article
Benzenesulfonyl chloride with primary and secondary amines in aqueous media — Unexpected high conversions to sulfonamides at high pH.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1525, doi. 10.1139/V05-154
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- Article
Formation and stability of organic zwitterions — The carbon acid pK<sub>a</sub>s of the trimethylsulfonium and tetramethylphosphonium cations in water.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1536, doi. 10.1139/V05-155
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- Article
Effect of modification of the electrophilic center on the α effect.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1365, doi. 10.1139/V05-157
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- Article
The role of molecular geometry in the Wolff rearrangement of α-diazocarbonyl compounds — Conformational control or structural constraints?
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1382, doi. 10.1139/V05-152
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- Article
Scientific genealogies of physical and mechanistic organic chemists.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1400, doi. 10.1139/V05-158
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- Article
A temperature-annealing effect on the host–guest complexation with γ-cyclodextrin.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1440, doi. 10.1139/V05-159
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- Article
Elimination reactions – Calculation of rate constants from equilibrium constants and distortion energies by means of no barrier theory.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1654, doi. 10.1139/V05-160
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- Article
Intramolecular general acid catalysis of sulfate transfer — Nucleophilic attack by oxyanions on the SO<sub>3</sub><sup>–</sup> group.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1629, doi. 10.1139/V05-172
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- Article
Acid enol and dihydropyridine intermediates in pyridylketene hydration — A computational study.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1561, doi. 10.1139/V05-162
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- Article
The mechanisms of hydrolysis of alkyl N-alkylthioncarbamate esters at 100 °C.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1483, doi. 10.1139/V05-165
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- Article
Regioselective S—O vs. C—O bond cleavage in sulfenate ester radical anions.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1473, doi. 10.1139/V05-164
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- Article
On the displacement reactions of organic substances in water.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1667, doi. 10.1139/V05-166
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- Article
Valence bond calculations on the transition state for the E2 reaction of fluoride ion with ethyl fluoride — Implications for the More O'Ferrall – Jencks diagram.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1649, doi. 10.1139/V05-161
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- Article
Deuterium kinetic isotope effects on the thermal isomerizations of deuteriocyclopropane to deuterium-labeled propenes.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1510, doi. 10.1139/V05-167
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- Article
The addition of alkynes to a tetrasilyldisilene — Evidence for a biradical intermediate.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1568, doi. 10.1139/V05-169
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- Article
Comparison of the nucleophilicities of alcohols and alkoxides.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1554, doi. 10.1139/V05-170
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- Article
Mechanism of the lithium–iodine exchange in an iodothiophene.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1577, doi. 10.1139/V05-173
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- Article
The kinetics of the spontaneous, proton- and Al<sup>III</sup>-catalysed hydrolysis of 1,5-anhydrocellobiitol — Models for cellulose depolymerization in paper aging and alkaline pulping, and a benchmark for cellulase efficiency.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1516, doi. 10.1139/V05-168
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- Article
Reaction intermediates in organic chemistry — The “big picture”.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1415, doi. 10.1139/V05-175
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- Article
Influence of the number of water molecules on the mechanism of N-sulfinylaniline hydrolysis.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1588, doi. 10.1139/V05-171
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- Article
S<sub>N</sub>2 and S<sub>N</sub>2′ reaction dynamics of cyclopropenyl chloride with halide ion — A direct ab initio molecular dynamics (MD) study.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1597, doi. 10.1139/V05-176
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- Article
Dissociation of the phenanthroimidazole dimer — A highly delocalized radical — Gomberg revisited.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1448, doi. 10.1139/V05-177
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- Article
Physical organic chemistry in Canada 1900–2005.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1197, doi. 10.1139/V05-178
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- Article
A computational study of the 1,3-dipolar cycloaddition reaction mechanism for nitrilimines.
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- Canadian Journal of Chemistry, 2005, v. 83, n. 9, p. 1615, doi. 10.1139/V05-179
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- Article