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Transition‐Metal‐Free Reductive Functionalization of Tertiary Carboxamides and Lactams for α‐Branched Amine Synthesis.
- Published in:
- Angewandte Chemie, 2020, v. 132, n. 29, p. 12001, doi. 10.1002/ange.202004272
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- Publication type:
- Article
Catalytic Enantioselective Direct Aldol Addition of Aryl Ketones to α‐Fluorinated Ketones.
- Published in:
- Angewandte Chemie, 2020, v. 132, n. 13, p. 5397, doi. 10.1002/ange.201916129
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- Publication type:
- Article
Dearomative Photocatalytic Construction of Bridged 1,3‐Diazepanes.
- Published in:
- Angewandte Chemie, 2020, v. 132, n. 10, p. 4150, doi. 10.1002/ange.201914390
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- Publication type:
- Article
One‐Pot Catalytic Enantioselective Synthesis of 2‐Pyrazolines.
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- Angewandte Chemie, 2019, v. 131, n. 8, p. 2491, doi. 10.1002/ange.201811471
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- Publication type:
- Article
Measuring Spin Relaxation Rates Using Satellite Exchange NMR Spectroscopy.
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- Angewandte Chemie, 2018, v. 130, n. 25, p. 7620, doi. 10.1002/ange.201801322
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- Publication type:
- Article
Thioamide-Directed Cobalt(III)-Catalyzed Selective Amidation of C(sp<sup>3</sup>)−H Bonds.
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- Angewandte Chemie, 2017, v. 129, n. 52, p. 16777, doi. 10.1002/ange.201709273
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- Publication type:
- Article
Enantioselective Silver and Amine Co-catalyzed Desymmetrizing Cycloisomerization of Alkyne-Linked Cyclohexanones.
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- Angewandte Chemie, 2017, v. 129, n. 21, p. 5928, doi. 10.1002/ange.201612048
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- Publication type:
- Article
Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation.
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- Angewandte Chemie, 2017, v. 129, n. 13, p. 3709, doi. 10.1002/ange.201612367
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- Publication type:
- Article
Expeditious and Divergent Total Syntheses of Aspidosperma Alkaloids Exploiting Iridium(I)-Catalyzed Generation of Reactive Enamine Intermediates.
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- Angewandte Chemie, 2016, v. 128, n. 43, p. 13634, doi. 10.1002/ange.201605503
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- Publication type:
- Article
Direct Catalytic Asymmetric Doubly Vinylogous Michael Addition of α,β-Unsaturated γ-Butyrolactams to Dienones.
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- Angewandte Chemie, 2015, v. 127, n. 35, p. 10387, doi. 10.1002/ange.201504276
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- Publication type:
- Article
LP99: Discovery and Synthesis of the First Selective BRD7/9 Bromodomain Inhibitor.
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- Angewandte Chemie, 2015, v. 127, n. 21, p. 6315, doi. 10.1002/ange.201501394
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- Publication type:
- Article
Enantioselective Desymmetrization of Prochiral Cyclohexanones by Organocatalytic Intramolecular Michael Additions to α,β-Unsaturated Esters.
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- Angewandte Chemie, 2015, v. 127, n. 16, p. 4981, doi. 10.1002/ange.201411924
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- Publication type:
- Article
Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates.
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- Angewandte Chemie, 2015, v. 127, n. 16, p. 4977, doi. 10.1002/ange.201411852
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- Publication type:
- Article
Catalytic Stereoselective Semihydrogenation of Alkynes to E-Alkenes.
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- Angewandte Chemie International Edition, 2013, v. 52, n. 3, p. 806, doi. 10.1002/anie.201208120
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- Article
Catalytic Enantio- and Diastereoselective Alkylations with Cyclic Sulfamidates.
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- Angewandte Chemie International Edition, 2010, v. 49, n. 3, p. 568, doi. 10.1002/anie.200905329
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- Article
Asymmetric Organocatalytic Relay Cascades: Catalyst-Controlled Stereoisomer Selection in the Synthesis of Functionalized Cyclohexanes.
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- Angewandte Chemie International Edition, 2009, v. 48, n. 52, p. 9834, doi. 10.1002/anie.200905014
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- Publication type:
- Article
Site-Isolated Base- and Acid-Mediated Michael-Initiated Cyclization Cascades.
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- Angewandte Chemie International Edition, 2007, v. 46, n. 28, p. 5428, doi. 10.1002/anie.200701079
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- Article
Iridium-Catalyzed Reductive Nitro-Mannich Cyclization.
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- Chemistry - A European Journal, 2015, v. 21, n. 1, p. 111, doi. 10.1002/chem.201405256
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- Article
Mechanistic Investigations into the Enantioselective Conia-Ene Reaction Catalyzed by Cinchona-Derived Amino Urea Pre-Catalysts and Cu<sup>I</sup>.
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- Chemistry - A European Journal, 2013, v. 19, n. 42, p. 14286, doi. 10.1002/chem.201200832
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- Article
Catalytic Asymmetric Alkylation Reactions for the Construction of Protected Ethylene-Amino and Propylene-Amino Motifs Attached to Quaternary Stereocentres.
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- Chemistry - A European Journal, 2013, v. 19, n. 9, p. 3071, doi. 10.1002/chem.201203825
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- Article
Efficient and Selective Formation of Macrocyclic Disubstituted Z Alkenes by Ring-Closing Metathesis (RCM) Reactions Catalyzed by Mo- or W-Based Monoaryloxide Pyrrolide (MAP) Complexes: Applications to Total Syntheses of Epilachnene, Yuzu Lactone, Ambrettolide, Epothilone C, and Nakadomarin A
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- Chemistry - A European Journal, 2013, v. 19, n. 8, p. 2726, doi. 10.1002/chem.201204045
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- Publication type:
- Article
Multiple-Organocatalyst-Promoted Cascade Reaction: A Fast and Efficient Entry into Fully Substituted Piperidines.
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- Chemistry - A European Journal, 2010, v. 16, n. 13, p. 3922, doi. 10.1002/chem.201000059
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- Article
Diastereodivergent organocatalytic asymmetric vinylogous Michael reactions.
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- Nature Communications, 2014, v. 5, n. 7, p. 4479, doi. 10.1038/ncomms5479
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- Publication type:
- Article
The Use of Butane Diacetals of Glycolic Acid as Precursors for the Synthesis of the Phytotoxic Calmodulin Inhibitor Herbarumin II.
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- Helvetica Chimica Acta, 2003, v. 86, n. 11, p. 3717
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- Article
Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis.
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- Nature, 2011, v. 479, n. 7371, p. 88, doi. 10.1038/nature10563
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- Publication type:
- Article
Measuring Spin Relaxation Rates Using Satellite Exchange NMR Spectroscopy.
- Published in:
- Angewandte Chemie International Edition, 2018, v. 57, n. 25, p. 7498, doi. 10.1002/anie.201801322
- By:
- Publication type:
- Article
Thioamide-Directed Cobalt(III)-Catalyzed Selective Amidation of C(sp<sup>3</sup>)−H Bonds.
- Published in:
- Angewandte Chemie International Edition, 2017, v. 56, n. 52, p. 16550, doi. 10.1002/anie.201709273
- By:
- Publication type:
- Article
Enantioselective Silver and Amine Co-catalyzed Desymmetrizing Cycloisomerization of Alkyne-Linked Cyclohexanones.
- Published in:
- Angewandte Chemie International Edition, 2017, v. 56, n. 21, p. 5834, doi. 10.1002/anie.201612048
- By:
- Publication type:
- Article
Iridium-Catalyzed Reductive Strecker Reaction for Late-Stage Amide and Lactam Cyanation.
- Published in:
- Angewandte Chemie International Edition, 2017, v. 56, n. 13, p. 3655, doi. 10.1002/anie.201612367
- By:
- Publication type:
- Article
Expeditious and Divergent Total Syntheses of Aspidosperma Alkaloids Exploiting Iridium(I)-Catalyzed Generation of Reactive Enamine Intermediates.
- Published in:
- Angewandte Chemie International Edition, 2016, v. 55, n. 43, p. 13436, doi. 10.1002/anie.201605503
- By:
- Publication type:
- Article
Direct Catalytic Asymmetric Doubly Vinylogous Michael Addition of α,β-Unsaturated γ-Butyrolactams to Dienones.
- Published in:
- Angewandte Chemie International Edition, 2015, v. 54, n. 35, p. 10249, doi. 10.1002/anie.201504276
- By:
- Publication type:
- Article
LP99: Discovery and Synthesis of the First Selective BRD7/9 Bromodomain Inhibitor.
- Published in:
- Angewandte Chemie International Edition, 2015, v. 54, n. 21, p. 6217, doi. 10.1002/anie.201501394
- By:
- Publication type:
- Article
Direct Catalytic Enantio- and Diastereoselective Ketone Aldol Reactions of Isocyanoacetates.
- Published in:
- Angewandte Chemie International Edition, 2015, v. 54, n. 16, p. 4895, doi. 10.1002/anie.201411852
- By:
- Publication type:
- Article
Enantioselective Desymmetrization of Prochiral Cyclohexanones by Organocatalytic Intramolecular Michael Additions to α,β-Unsaturated Esters.
- Published in:
- Angewandte Chemie International Edition, 2015, v. 54, n. 16, p. 4899, doi. 10.1002/anie.201411924
- By:
- Publication type:
- Article
Direct Catalytic Enantio- and Diastereoselective Mannich Reaction of Isocyanoacetates and Ketimines.
- Published in:
- Angewandte Chemie International Edition, 2014, v. 53, n. 13, p. 3462, doi. 10.1002/anie.201309719
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- Publication type:
- Article
The Total Synthesis of the Annonaceous Acetogenin 10-Hydroxyasimicin.
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- Angewandte Chemie, 2005, v. 117, n. 4, p. 586, doi. 10.1002/ange.200462264
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- Publication type:
- Article
Highly Diastereoselective Oxy-Michael Additions of Enantiopure δ-Lactol Anions to Nitroalkenes: Asymmetric Synthesis of 1,2-Amino AlcoholsWe gratefully acknowledge the support of GlaxoSmithKline and Prof. S. V. Ley. We are also indebted to Dr. John E. Davis for the X-ray structure determinations and Dr. D. Hepworth for useful discussions.
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- Angewandte Chemie, 2003, v. 115, n. 35, p. 4373, doi. 10.1002/ange.200352007
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- Publication type:
- Article
Iridium-catalyzed reductive Ugi-type reactions of tertiary amides.
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- Nature Communications, 2018, v. 9, n. 1, p. 1, doi. 10.1038/s41467-018-05192-7
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- Publication type:
- Article
Second Generation Catalytic Enantioselective Nucleophilic Desymmetrization at Phosphorus (V): Improved Generality, Efficiency and Modularity.
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- Angewandte Chemie International Edition, 2024, v. 63, n. 18, p. 1, doi. 10.1002/anie.202400673
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- Publication type:
- Article
Cobalt‐Catalyzed Enantio‐ and Regioselective C(sp<sup>3</sup>)−H Alkenylation of Thioamides.
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- Angewandte Chemie International Edition, 2024, v. 63, n. 13, p. 1, doi. 10.1002/anie.202316021
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- Publication type:
- Article
Bifunctional Iminophosphorane Catalyzed Amide Enolization for Enantioselective Cyclohexadienone Desymmetrization.
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- Angewandte Chemie International Edition, 2024, v. 63, n. 5, p. 1, doi. 10.1002/anie.202315401
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- Publication type:
- Article
Enantioselective Total Synthesis of (+)‐Incargranine A Enabled by Bifunctional Iminophosphorane and Iridium Catalysis.
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- Angewandte Chemie International Edition, 2024, v. 63, n. 2, p. 1, doi. 10.1002/anie.202314308
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- Publication type:
- Article
Bifunctional Iminophosphorane‐Catalyzed Enantioselective Nitroalkane Addition to Unactivated α,β‐Unsaturated Esters**.
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- Angewandte Chemie International Edition, 2023, v. 62, n. 21, p. 1, doi. 10.1002/anie.202303391
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- Publication type:
- Article
Switchable, Reagent‐Controlled Diastereodivergent Photocatalytic Carbocyclisation of Imine‐Derived α‐Amino Radicals.
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- Angewandte Chemie International Edition, 2021, v. 60, n. 45, p. 24116, doi. 10.1002/anie.202107253
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- Publication type:
- Article
General α‐Amino 1,3,4‐Oxadiazole Synthesis via Late‐Stage Reductive Functionalization of Tertiary Amides and Lactams**.
- Published in:
- Angewandte Chemie International Edition, 2021, v. 60, n. 36, p. 19725, doi. 10.1002/anie.202107536
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- Publication type:
- Article
BIMP‐Catalyzed 1,3‐Prototropic Shift for the Highly Enantioselective Synthesis of Conjugated Cyclohexenones.
- Published in:
- Angewandte Chemie International Edition, 2020, v. 59, n. 40, p. 17417, doi. 10.1002/anie.202006202
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- Publication type:
- Article
Transition‐Metal‐Free Reductive Functionalization of Tertiary Carboxamides and Lactams for α‐Branched Amine Synthesis.
- Published in:
- Angewandte Chemie International Edition, 2020, v. 59, n. 29, p. 11903, doi. 10.1002/anie.202004272
- By:
- Publication type:
- Article
Catalytic Enantioselective Direct Aldol Addition of Aryl Ketones to α‐Fluorinated Ketones.
- Published in:
- Angewandte Chemie International Edition, 2020, v. 59, n. 13, p. 5359, doi. 10.1002/anie.201916129
- By:
- Publication type:
- Article
Dearomative Photocatalytic Construction of Bridged 1,3‐Diazepanes.
- Published in:
- Angewandte Chemie International Edition, 2020, v. 59, n. 10, p. 4121, doi. 10.1002/anie.201914390
- By:
- Publication type:
- Article
One‐Pot Catalytic Enantioselective Synthesis of 2‐Pyrazolines.
- Published in:
- Angewandte Chemie International Edition, 2019, v. 58, n. 8, p. 2469, doi. 10.1002/anie.201811471
- By:
- Publication type:
- Article