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- Title
Spin-State Photoswitching Dynamics of the [(TPA)Fe(TCC)]SbF<sub>6</sub> Complex.
- Authors
Kaszub, Wawrzyniec; Buron‐Le Cointe, Marylise; Lorenc, Maciej; Boillot, Marie‐Laure; Servol, Marina; Tissot, Antoine; Guérin, Laurent; Cailleau, Hervé; Collet, Eric
- Abstract
We report on the spin state photoswitching dynamics triggered by a femtosecond laser of [(TPA)FeIII(TCC)]+ cations in a new salt with SbF6- anions. Femtosecond optical pump-probe spectroscopy and picosecond X-ray diffraction techniques were combined to investigate the different steps of the out-of-equilibrium dynamics. The obtained results are very consistent with the ones previously reported for the PF6- salts. If the ultra-fast responses of the cations in both salts are similar, the spin conversion due to laser heating is slightly shifted to higher temperature in the SbF6- salt, as its thermal crossover occurs at higher temperature.
- Subjects
SPIN crossover; FEMTOSECOND lasers; ANIONS; CATIONS; X-ray diffraction
- Publication
European Journal of Inorganic Chemistry, 2013, Vol 2013, Issue 5/6, p992
- ISSN
1434-1948
- Publication type
Article
- DOI
10.1002/ejic.201201083