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- Title
Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí (Euterpe oleracea Mart.) Seeds Pyrolysis.
- Authors
Rocha de Castro, Douglas Alberto; da Silva Ribeiro, Haroldo Jorge; Hamoy Guerreiro, Lauro Henrique; Pinto Bernar, Lucas; Jonatan Bremer, Sami; Costa Santo, Marcelo; da Silva Almeida, Hélio; Duvoisin Jr., Sergio; Pizarro Borges, Luiz Eduardo; Teixeira Machado, Nélio
- Abstract
This work investigates the effect of production scales (laboratory, bench, and pilot) by pyrolysis of Açaí (Euterpe oleracea Mart.) seeds at 450 °C and 1.0 atmosphere, on the yields of reaction products and acid value of bio-oils. The experiments were carried out in batch mode using a laboratory scale reactor of 143 mL, a bench scale reactor of 1.5 L, and a pilot scale reactor of 143 L (≈1:10:1000). The bio-oil was obtained in pilot scale, fractionated by distillation to produce biofuel-like fractions. The distillation of bio-oil was carried out in a laboratory column. The physical-chemistry properties (density, kinematic viscosity, acid value, and refractive index) of bio-oils and distillation fractions were determined. The qualitative analysis was determined by FT-IR and the chemical composition by GC-MS. The pyrolysis showed bio-oil yields from 4.37 to 13.09 (wt.%), decreasing with reactor volume. The acid value of bio-oils varied from 68.31 to 70.26 mg KOH/g. The distillation of bio-oil produced gasoline, light kerosene, and kerosene-like fuel fractions, and the yields were 16.16, 19.56, and 41.89 (wt.%), respectively. The physical-chemistry properties of distillation fractions increase with temperature. The FT-IR analysis of bio-oils and distillation fractions identified the presence of functional groups characteristic of hydrocarbons (alkenes, alkanes, aromatics, and aromatics rings) and oxygenates (carboxylic acids, ketones, esters, ethers, alcohols, phenols). The GC-MS identified 48.24 (area.%) hydrocarbons and 51.76 (area.%) oxygenates in the bio-oil produced in bench scale and 21.52 (area.%) hydrocarbons and 78.48 (area.%) oxygenates in the bio-oil produced in pilot scale. The gasoline-like fraction was composed by 64.0 (area.%) hydrocarbons and 36.0 (area.%) oxygenates, light kerosene-like fraction by 66.67 (area.%) hydrocarbons and 33.33 (area.%) oxygenates, and kerosene-like fraction by 19.87 (area.%) hydrocarbons and 81.13 (area.%) oxygenates.
- Subjects
FRACTIONAL distillation; ACAI palm; KINEMATIC viscosity; PYROLYSIS; GASOLINE; CHEMICAL yield; ESSENTIAL oils
- Publication
Energies (19961073), 2021, Vol 14, Issue 13, p3713
- ISSN
1996-1073
- Publication type
Article
- DOI
10.3390/en14133713