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- Title
A Hydrolytically Stable Vanadium(IV) Metal–Organic Framework with Photocatalytic Bacteriostatic Activity for Autonomous Indoor Humidity Control.
- Authors
Ma, Dou; Li, Ping; Duan, Xiangyu; Li, Jiazhen; Shao, Pengpeng; Lang, Zhongling; Bao, Lixia; Zhang, Yuanyuan; Lin, Zhengguo; Wang, Bo
- Abstract
Metal–organic frameworks (MOFs) with long‐term stability and reversible high water uptake properties can be ideal candidates for water harvesting and indoor humidity control. Now, a mesoporous and highly stable MOF, BIT‐66 is presented that has indoor humidity control capability and a photocatalytic bacteriostatic effect. BIT‐66 (V3(O)3(H2O)(BTB)2), possesses prominent moisture tunability in the range of 45–60 % RH and a water uptake and working capacity of 71 and 55 wt %, respectively, showing good recyclability and excellent performance in water adsorption–desorption cycles. Importantly, this MOF demonstrates a unique photocatalytic bacteriostatic behavior under visible light, which can effectively ameliorate the bacteria and/or mold breeding problem in water adsorbing materials.
- Subjects
HUMIDITY control; METAL-organic frameworks; WATER harvesting; VISIBLE spectra; HYDROLOGIC cycle; ORGANIC water pollutants; VANADIUM; MAGNESIUM hydride
- Publication
Angewandte Chemie, 2020, Vol 132, Issue 10, p3933
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201914762