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- Title
Atom‐Economic Silver‐Catalyzed Difunctionalization of the Isocyano Group with Cyclic Oximes: Towards Pyrimidinediones.
- Authors
Liang, Hong‐Wen; Yang, Zhen; Jiang, Kun; Ye, Ying; Wei, Ye
- Abstract
Abstract: An unprecedented silver‐catalyzed difunctionalization of the isocyano group with cyclic oximes is described. This method allows efficient and atom‐economic assembly of a vast array of structurally novel and interesting pyrimidinediones, and tolerates a range of functionalities. The resulting products can be easily converted into some useful compounds. Furthermore, the method can also be applied for the late‐stage modification of a few biologically active molecules.
- Subjects
SILVER catalysts; URACIL; CYANO group; BENZOPHENONES; ISOCYANIDES; SODIUM sulfate
- Publication
Angewandte Chemie, 2018, Vol 130, Issue 20, p5822
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201801363