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- Title
Catalytic Enantioselective Assembly of Homoallylic Alcohols from Dienes, Aryldiazonium Salts, and Aldehydes.
- Authors
Tao, Zhong‐Lin; Adili, Alafate; Shen, Hong‐Cheng; Han, Zhi‐Yong; Gong, Liu‐Zhu
- Abstract
A highly selective multicomponent carbonyl allylation reaction of 1,3-butadienes, aryldiazonium tetrafluoroborates, and aldehydes has been established under the combined catalysis of palladium acetate and chiral anion phase transfer to render the favorable assembly of chiral Z-configured homoallylic alcohols in high yields and with excellent levels of enantioselectivity.
- Subjects
ASYMMETRIC synthesis; DIOLEFINS synthesis; ALLYL alcohol synthesis; ALDEHYDE synthesis; DIAZONIUM compounds; PALLADIUM catalysts; PHASE-transfer catalysis
- Publication
Angewandte Chemie, 2016, Vol 128, Issue 13, p4394
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201600148