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- Title
Uncovering the Role of Metal Catalysis in Tetrazole Formation by an In Situ Cycloaddition Reaction: An Experimental Approach.
- Authors
Zhong, Di ‐ Chang; Wen, Ya ‐ Qiong; Deng, Ji ‐ Hua; Luo, Xu ‐ Zhong; Gong, Yun ‐ Nan; Lu, Tong ‐ Bu
- Abstract
Using an experimental approach, the role of metal catalysis has been investigated in the in situ cycloaddition reaction of nitrile with azide to form tetrazoles. It has been shown that metal catalysis serves to activate the cyano group in the nitrile reagent by a coordinative interaction.
- Subjects
TETRAZOLES; RING formation (Chemistry); METAL catalysts; NITRILES; CYANO group; MOLECULAR interactions; COORDINATION number (Chemistry)
- Publication
Angewandte Chemie, 2015, Vol 127, Issue 40, p11961
- ISSN
0044-8249
- Publication type
Article
- DOI
10.1002/ange.201505118