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- Title
Coordination Polymer Nanobamboos of {Fe<sub> x</sub>In<sub>1− x</sub>}-MIL-88B: Induced Formation of a Virtual In-MIL-88B.
- Authors
Park, Shin Ae; Lee, Hee Jung; Cho, Yea Jin; Choi, Sora; Oh, Moonhyun
- Abstract
A precise fabrication of nanobamboo structures made from hybrid coordination polymers of the type {Fe xIn1− x}-MIL-88B is demonstrated. The compositions of the hybrid coordination polymer nanobamboos of {Fe xIn1− x}-MIL-88B ( x=0.06, 0.19, or 0.75) are regulated by altering the amount of metal ions used in the reactions. Interestingly, the formation of a virtual In-MIL-88B (precise structure, {Fe0.06In0.94}-MIL-88B), which cannot be created in a typical reaction, is induced by the assistance of a Fe-MIL-88B structure. The a and c cell parameters of {Fe0.06In0.94}-MIL-88B are calculated at 10.95 and 19.86 Å, respectively. These values of {Fe0.06In0.94}-MIL-88B are larger than those of pure Fe-MIL-88B owing to the large ionic size of In3+ within the framework.
- Subjects
POLYMERS; METAL ions; INTERMEDIATES (Chemistry); COORDINATION polymers; SOLUTION (Chemistry); CHROMIUM ions
- Publication
Chemistry - A European Journal, 2014, Vol 20, Issue 19, p5559
- ISSN
0947-6539
- Publication type
Article
- DOI
10.1002/chem.201304515