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- Title
Ligandless C-C bond formation via.
- Authors
Hoseini, S. Jafar; Zarei, Atiyeh; Rafatbakhsh Iran, Hajar
- Abstract
PdPtZn and PdZn nanoparticle (NP) were synthesized by the reduction of [PdCl2(cod)], [PtCl2(cod)] (cod = cis, cis-1,5-cyclooctadiene) and [Zn(acac)2] (acac = acetylacetonate) complexes at an oil-water interface. The structure and morphology of the as-prepared NPs were characterized with X-ray diffraction, transmission and energy dispersive analysis of X-rays. of the prepared NPs was investigated in the in H2O-EtOH and various micellar media systems such as cetyltrimethylammonium bromide (cationic surfactant), sodium dodecylsulfate (anionic surfactant) and Pluronic P123 (non-ionic surfactant). PdPtZn and PdZn exhibited higher compared to Pd in the due to the appropriate interaction between palladium, platinum and zinc metals. Copyright © 2015 John Wiley & Sons, Ltd.
- Subjects
CARBON-carbon bonds synthesis; SUZUKI reaction; MICELLES; PLATINUM nanoparticles; X-ray diffraction
- Publication
Applied Organometallic Chemistry, 2015, Vol 29, Issue 8, p489
- ISSN
0268-2605
- Publication type
Article
- DOI
10.1002/aoc.3318